以钢渣、磷酸渣和石灰石粉为原料制备高活性掺合料

4区 材料科学 Q2 Environmental Science Journal of Renewable Materials Pub Date : 2023-01-01 DOI:10.32604/jrm.2023.028439
Ying Ji, Xi Liu
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引用次数: 0

摘要

大宗工业固体废物处理利用率低的问题亟待解决。本文针对大多数活性低、对混凝土和易性有负面影响的固体废物,结合各固体废物的特点,提出了一种由钢渣-磷酸渣-石灰石粉组成的高活性掺合料。结合物相组成、水化温度、微观形貌,从标准稠度需水量、凝结时间、和易性、力学性能等方面论证了复合体系的可行性,阐述了复合体系的原理。结果表明,钢渣:磷酸渣:石灰石= 5:2:3的复合体系活性最高,达到92%以上。此外,与水泥相比,复合体系对需水量和凝结时间没有显著影响,但能显著提高体系的7 d和28 d活性。复合体系延缓了水泥的放热水化,降低了放热热量,但对水化产物没有影响。因此,本文的研究显著提高了混凝土中固体废物的耗散,减少了混凝土中的水泥用量,积极响应了国家碳中和和调峰的口号。
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Preparation of High Activity Admixture from Steel Slag, Phosphate Slag and Limestone Powder
The problem of low disposal and utilization rate of bulk industrial solid waste needs to be solved. In this paper, a high-activity admixture composed of steel slag-phosphate slag-limestone powder was proposed for most of the solid waste with low activity and a negative impact on concrete workability, combining the characteristics of each solid waste. The paper demonstrates the feasibility and explains the principle of the composite system in terms of water requirement of standard consistency, setting time, workability, and mechanical properties, combined with the composition of the phases, hydration temperature, and microscopic morphology. The results showed that the steel slag:phosphate slag:limestone = 5:2:3 gave the highest activity of the composite system, over 92%. Besides, the composite system had no signi fi cant effect on water demand and setting time compared to cement, and it could signi fi cantly increase the 7 and 28 d activity of the system. The composite system delayed the exothermic hydration of the cement and reduced the exothermic heat but had no effect on the hydration products. Therefore, the research in this paper dramatically improved the solid waste dissipation in concrete, reduced the amount of cement in concrete and positively responded to the national slogan of carbon neutral and peaking.
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来源期刊
Journal of Renewable Materials
Journal of Renewable Materials Materials Science, Composites; Polymer Science; Green & Sustainable Science & Technology-
CiteScore
4.10
自引率
0.00%
发文量
125
期刊介绍: This journal publishes high quality peer reviewed original research and review articles on macromolecules and additives obtained from renewable/biobased resources. Utilizing a multidisciplinary approach, JRM introduces cutting-edge research on biobased monomers, polymers, additives (both organic and inorganic), their blends and composites. JRM showcases both fundamental aspects and applications of renewable materials. The fundamental topics include the synthesis and polymerization of biobased monomers and macromonomers, the chemical modification of natural polymers, as well as the characterization, structure-property relationships, processing, recycling, bio and environmental degradation and life cycle analysis of the ensuing materials, in view of their potential applications. Within this sustainability approach, green chemistry processes and studies falling within biorefinery contexts are strongly favored.
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