基于随机粒子概念的熔点热、沸点热与自扩散活化能的关系

V. P. Malyshev, A. Makasheva
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引用次数: 4

摘要

以典型金属为例,发现自扩散活化能大于熔化热,小于汽化热。这对应于基于随机粒子概念的液体移动粒子分类的存在。提出了一种估算自扩散活化能的公式,该公式约为物质蒸发热的一半。我们推导了部分自扩散粒子的温度依赖关系。
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The Relation between the Heat of Melting Point, Boiling Point, and the Activation Energy of Self-Diffusion in Accordance with the Concept of Randomized Particles
On the example of typical metals, it’s found that the activation energy of self-diffusion is above of the melting heat and below of vaporization heat. This corresponds to the existence of liquid-mobile particle classification based on the concept of randomized particles. A formula for estimating the activation energy of self-diffusion by which it is approximately half of the heat of evaporation of the substance is recommended. We derive the temperature dependence for a fraction self-diffusion’s particles.
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