{"title":"基于随机粒子概念的熔点热、沸点热与自扩散活化能的关系","authors":"V. P. Malyshev, A. Makasheva","doi":"10.4236/OJPC.2014.44019","DOIUrl":null,"url":null,"abstract":"On the example of typical metals, it’s found that the activation energy of self-diffusion is above of the melting heat and below of vaporization heat. This corresponds to the existence of liquid-mobile particle classification based on the concept of randomized particles. A formula for estimating the activation energy of self-diffusion by which it is approximately half of the heat of evaporation of the substance is recommended. We derive the temperature dependence for a fraction self-diffusion’s particles.","PeriodicalId":59839,"journal":{"name":"物理化学期刊(英文)","volume":"04 1","pages":"166-172"},"PeriodicalIF":0.0000,"publicationDate":"2014-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":"{\"title\":\"The Relation between the Heat of Melting Point, Boiling Point, and the Activation Energy of Self-Diffusion in Accordance with the Concept of Randomized Particles\",\"authors\":\"V. P. Malyshev, A. Makasheva\",\"doi\":\"10.4236/OJPC.2014.44019\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"On the example of typical metals, it’s found that the activation energy of self-diffusion is above of the melting heat and below of vaporization heat. This corresponds to the existence of liquid-mobile particle classification based on the concept of randomized particles. A formula for estimating the activation energy of self-diffusion by which it is approximately half of the heat of evaporation of the substance is recommended. We derive the temperature dependence for a fraction self-diffusion’s particles.\",\"PeriodicalId\":59839,\"journal\":{\"name\":\"物理化学期刊(英文)\",\"volume\":\"04 1\",\"pages\":\"166-172\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2014-10-15\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"物理化学期刊(英文)\",\"FirstCategoryId\":\"1089\",\"ListUrlMain\":\"https://doi.org/10.4236/OJPC.2014.44019\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"物理化学期刊(英文)","FirstCategoryId":"1089","ListUrlMain":"https://doi.org/10.4236/OJPC.2014.44019","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The Relation between the Heat of Melting Point, Boiling Point, and the Activation Energy of Self-Diffusion in Accordance with the Concept of Randomized Particles
On the example of typical metals, it’s found that the activation energy of self-diffusion is above of the melting heat and below of vaporization heat. This corresponds to the existence of liquid-mobile particle classification based on the concept of randomized particles. A formula for estimating the activation energy of self-diffusion by which it is approximately half of the heat of evaporation of the substance is recommended. We derive the temperature dependence for a fraction self-diffusion’s particles.