由饱和原子组成的分子化合物在液相中的稳定性:应用奇偶规则和特定的液体元素周期表

G. Auvert, M. Auvert
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引用次数: 0

摘要

基于液相分子通过共价键缔合成多分子复合物的思想,本文重点讨论了这些复合物的可能结构。原子水平上的饱和是理解连接发生的位置和分子聚集的距离的关键概念。根据奇偶规则,提出了含饱和水平的液体周期表,包括有机元素和无机元素。为了达到最稳定的配合物,即在液相中不发生其他化学反应,设计了由大约30个分子液化产生的配合物的结构。文章的结论是,液体中的配合物通常呈圆形,介于气体和固体结构之间。结果表明,仅用饱和键和共价键就可以解释液体的特定性质。虽然人们普遍认为气体和固体中的分子能量分别是线性动能和振动动能,但我们认为液体中的分子能量主要是旋转能。
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Stability in Liquid Phases of Molecular Compounds Composed of Saturated Atoms: Application with the Even-Odd Rule and a Specific Periodic Table for Liquids
Building on the idea that molecules in liquid phase associate into multi-mo-lecular complexes through covalent bonds, the present article focuses on the possible structures of these complexes. Saturation at atomic level is a key concept to understand where connections occur and how far molecules ag-gregate. A periodic table for liquids with saturation levels is proposed, in agreement with the even-odd rule, for both organic and inorganic elements. With the aim at reaching the most stable complexes, meaning no other chemical reactions can occur in the liquid phase, the structure of complexes resulting from liquefaction of about 30 molecules is devised. The article concludes that complexes in liquids generally assume rounded shapes of an intermediate size between gas and solid structures. It shows that saturation and covalent bonds alone can explain the specific properties of liquids. While it is generally ac-knowledged that molecular energy in gases and solids are respectively linear kinetic and vibratory, we suggest that rotatory energy dominates in liquids.
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