镀锌钢阳极氧化纳米氧化锌膜的生长

Henrique Gonçalves Pereira, Rubens Camaratta, Cristiane Wienke Raubach Ratmann, Naiane Paiva Stochero
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引用次数: 0

摘要

氧化锌(ZnO)是一种宽带隙半导体(3.37 eV),具有广泛的应用,如催化剂,压电致动器和换能器,太阳能电池,微传感器等。获得氧化锌的一种方法是通过金属锌的可控氧化,金属锌是世界上消费量第三大的有色金属,镀锌工业约占全球氧化锌消费量的57%。阳极氧化是一种表面处理过程,包括在金属表面形成氧化膜,能够保留大量的染料。将镀锌钢在5mM NaHCO3电解溶液中以35V恒电压、0.2A初始电流氧化8分钟得到ZnO。验证了阳极氧化表面的化学性质、层厚度和所获得的形貌,验证了其生产直径约为100nm的na-nofios。N479黑色染料的商业染料沉积。结果表明,得到了一层均匀的纳米线,其形貌具有很强的染料吸收层数。
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Crescimento de filme de ZnO nanoestruturado por anodização de aço galvanizado
Zinc oxide (ZnO) is a broad bandgap semiconductor (3.37 eV) with a wide range of applications, such as catalysts, piezoelectric actuators and transducers, solar cells, microsensors, among others. One way of obtaining ZnO is through the controlled oxidation of metallic zinc, which is the third most consumed metal in the world among the non-ferrous metals with the galvanizing industry being responsible for approximately 57% of the worldwide consumption of this metal. Anodizing is a process of surface treatment consisting of creating an oxide film on the metal surface, being able to retain large amounts of dye. ZnO was obtained by anodizing the galvanized steel which was carried out in a 5mM NaHCO3 electrolytic solution at a constant voltage of 35V with an initial current of 0.2A for 8 minutes. Chemical characterization of the anodized surface, thickness of the layer and verification of the morphology obtained were verified, where it was verified the production of na-nofios with about 100nm of diameter. N479 Black Dye commercial dye was deposited. The results showed the obtaining of a homogeneous layer, with the morphology of nanowires with great layer-city of dye absorption.
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发文量
40
审稿时长
12 weeks
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