气体污染物对银器光泽影响的勘误,Vol. 6 (2017), 135-148

Y. Salem
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摘要

塞勒姆,Y.(2017)气体污染物对银器光泽的影响。空气污染学报,6,135-148。不幸的是,Doi: 10.4236/ojap.2017.64011包含语法错误。作者希望改正这些错误。摘要本文研究了常见气体污染物对银制品的影响。这项研究是在由银合金(91银和9%铜)制成的券上进行的,其化学成分与古埃及银器相似。这些优惠券分别暴露于二氧化硫、二氧化氮、二氧化碳、硫化氢和氯等气体污染物中。在每一种气体浓度为10ppm的气候室中,暴露期为四周。每次试验结束后,通过SEM和PM检查来评估每种气体的效果,并观察形成的光泽层。结果表明,除二氧化碳外,所有气体都与表面发生反应。所形成的无光层的覆盖度和密度率各不相同,以h2s粉层最重。对试样进行XRD分析,结果表明,腐蚀产物为Ag 2s、AgCl、Ag 2so4、Ag(no3) 3 (NO) 3、AgO和Ag 2o。
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Erratum to the Influence of Gaseous Pollutants on Silver Artifacts Tarnishing, Vol. 6 (2017), 135-148
The original online version of this article Salem, Y. (2017) The Influence of Gaseous Pollutants on Silver Artifacts Tarnishing. Open Journal of Air Pollution, 6, 135-148. doi: 10.4236/ojap.2017.64011 unfortunately contains grammar mistakes. The author wishes to correct the errors. Abstract The present work investigated the effect of common gaseous pollutants on silver artifacts. The study was carried out on coupons made of a silver alloy (91 silver and 9% copper) with chemical composition similar to ancient Egyptian silver artifacts. These coupons were exposed to gaseous pollutants such as sulfur dioxide, nitrogen dioxide, carbon dioxide, hydrogen sulfide and chlorine, each gas separately. The exposure period was four weeks inside a climate chamber with 10 PPM concentration of each gas. After each test, examinations by SEM and PM were used to evaluate the effect of each gas and observe the formed tarnish layers. The results revealed that all gases reacted with the surface except carbon dioxide. The formed tarnish layers varied in coverage and density rate, and the heaviest layer was of H 2 S coupons. The tested coupons were analyzed by XRD and the results revealed Ag 2 S, AgCl, Ag 2 SO 4 , Ag(NO 3 ) 3 (NO) 3 , AgO and Ag 2 O as corrosion products.
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