Kravana(Kozie chrbta,斯洛伐克东部)遗址二叠纪中基粒火山中具有U-Mo-Cu矿化的Cremine碳酸盐岩脉

Q3 Earth and Planetary Sciences Bulletin Mineralogie Petrologie Pub Date : 2020-01-01 DOI:10.46861/bmp.28.364
Štefan Ferenc, Tomáš Mikuš, Ján Spišiak, Richard Kopáčik, Eva Hoppanová
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引用次数: 0

摘要

历史悠久的铀矿床Kravany位于Kozie Chrbty Mts.东部,位于Poprad镇西南约9公里处。层状、浸润型U-Cu-Pb成矿作用与上二叠统碎屑沉积物(Hronicum单元Malužiná组Kravany层)相结合,富集炭化植物群片段。在上二叠统中基性火山岩中发现脉状U-Mo-Cu矿化,与克拉瓦尼层(也称矿石透镜体)的沉积物相交。静脉充盈起源于以下几个发展阶段:石英-黄铁矿(石英、黄铁矿、黄铁矿)白云石-黄铁矿(白云石、黄铁矿、黄铁矿、方铅矿),III.)铜(四面体,tennantite,黄铜矿),IV.)铀钼(铀矿,Pb-Mo-S相,coffinite,石英),和V.)方解石(方解石、黄铜矿)。成矿作用的形成可以用地质位置来解释:闪长斑岩等的随机侵位。玄武岩-安山岩岩脉,直接存在于先前存在的含U、mo的沉积物中。脉状U- mo - cu矿化很可能是在以下情况下形成的:1)二叠系裂陷盆地克拉瓦尼床的沉积作用:含大量焦化植物群碎片的粗砂岩和粗砂岩床的形成;2)浸润型U矿化作用的形成:富有机质沉积物中U的还原和富集;3)中基性火山岩岩脉的侵位作用。沉积物与有机物和高U、Mo含量的交汇,地层流体的动员,U、Mo向中基性岩浆的同化,IV.)火山岩降温→收缩(形成收缩裂缝)→石英、碳酸盐和矿石矿物填充收缩裂缝(与地层水混合的残余岩浆溶液结晶)。从这个角度来看,它是同生的火山脉状U-Mo-Cu矿化,最初是在二叠纪,后来被高山(很可能是白垩纪)改造(这一点可以从铀矿的变化成分中得到证明)。属于新海西期晚-后成矿阶段。也必须假设高山热液溶液的矿化可能更年轻,在二叠纪之后,但这种考虑有几个不一致之处。
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Kremeňovo-karbonátové žily s U-Mo-Cu mineralizáciou v permských intermediárnych až bázických vulkanitoch hronika na lokalite Kravany (Kozie chrbty, východné Slovensko)
Historical uranium ore deposit Kravany is located in the eastern part of Kozie Chrbty Mts., approximately 9 km SW of the district town Poprad. Stratiform, infiltration U-Cu-Pb mineralization is bound to the Upper Permian clastic sediments (Kravany Beds, member of Malužiná Formation, Hronicum Unit), which are enriched in fragments of carbonized flora. Vein U-Mo-Cu mineralization was found in the Upper Permian intermediate to basic volcanics intersecting the sediments of the Kravany Beds (also ore lenses). Vein filling originated in the following development stages: I.) Quartz-pyrite (quartz, pyrite, marcasite), II.) Dolomite-pyrite (dolomite, pyrite, marcasite, galena), III.) Copper (tetrahedrite, tennantite, chalcopyrite), IV.) Uranium-molybdenum (uraninite, Pb-Mo-S phase, coffinite, quartz), and V.) Calcite (calcite, chalcopyrite). The formation of mineralization can be explained by the geological position: random emplacement of the diorite porphyrite, resp. basalt-andesite dikes, directly in the preexisting U,Mo-bearing sediments. Vein U-Mo-Cu mineralization could thus most likely have formed according to the following scenario: I.) sedimentation of Kravany Beds in the Permian riftogenic basin: formation of beds of arkoses and arkosic sandstones with abundant fragments of charred flora, II.) formation of infiltration U mineralization: reduction and accumulation of U in sediments rich in organic matter, III.) emplacement of dikes of intermediate to basic volcanics: intersection of sediments with organics and with high U and Mo content, mobilization of formation fluids, assimilation of U and Mo into intermediate-basic magma, IV.) cooling of volcanic bodies → their contraction (formation of contraction cracks) → filling of contraction cracks with quartz, carbonates and ore minerals (crystallization from residual magmatic solutions mixed with formation waters). From this point of view it is syngenetic volcanogenic vein U-Mo-Cu mineralization, originally of the Permian age, with subsequent Alpine (most probably Cretaceous) reworking (this is evidenced by the variable composition of uraninite). It belongs to the Neohercynian late- to postorogenic metallogenetic stage. The possible younger, post-Permian age of mineralization from alpine hydrothermal solutions must also be assumed, but this consideration has several inconsistencies.
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来源期刊
Bulletin Mineralogie Petrologie
Bulletin Mineralogie Petrologie Earth and Planetary Sciences-Economic Geology
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期刊介绍: Bulletin Mineralogie Petrologie is a peer-reviewed journal focused especially on: mineralogy, crystal chemistry and study of crystal structures of minerals study of mineral associations and processes of their origin meteoritics, research of tectites economic geology (of ore deposits) and study of history of mining of ore deposits topographic mineralogy petrology of igneous, metamorphic and sedimentary rocks instrumental analytical methods at mineralogy and petrology mineralogy and petrology as tools for archeology and similar disciplines
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