Chřibů山麓多文化考古遗址Boršice的铁渣

Q3 Earth and Planetary Sciences Bulletin Mineralogie Petrologie Pub Date : 2023-01-01 DOI:10.46861/bmp.31.018
Z. Dolníček, Ladislav Kandrnál, Jana Ulmanová
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引用次数: 0

摘要

在捷克共和国Chřiby山脉东南缘Boršice附近的考古遗址发现了一块铁渣,该遗址因新石器时代早期(公元前5700 - 5000年)、青铜时代和中世纪早期的文物而闻名。本文介绍了该渣的实验室研究结果。主要由铁矾石板条组成,分两代,较少出现玻璃相、钨铁、白闪石,也有金属铁。fayalite的组成具有统一的化学趋势,且范围较窄(fa93.7 ~ 96.3 dcs1.1 ~ 5.8 fo0.0 ~ 5.0 te0.0 ~ 0.2)。玻璃相除了含有常见的化合物(Si, Fe, Al,碱)外,还含有较高的P和Ca含量。在所研究的渣的微观结构以及各个相的化学性质在整个样品中非常均匀。我们将此渣解释为铁冶炼渣,起源于用直接法从矿石中生产铁的过程。所使用的矿石很可能是褐铁矿沼泽矿石,而根据所记录的相组成和个别相的化学组成,不太可能使用当地新鲜和(或)风化的pelosiderites。
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Železářská struska z polykulturní archeologické lokality Boršice v podhůří Chřibů
A piece of iron slag was found on an archaeological site near Boršice on the SE margin of the Chřiby Mts., Czech Republic, which is known by occurrence of artifacts from the Early Neolithic (5700 - 5000 BC), Bronze and Early Medieval Ages. We present results of laboratory investigation of this slag. It is composed mainly of fayalite laths, which belong to two generations, less occur glass phase, wüstite and leucite, exceptionally also metallic iron. The composition of fayalite displays unified chemical trend and ranges in rather narrow span (Fa93.7-96.3 DCS1.1-5.8Fo0.0-5.0Te0.0-0.2). The glass phase contains in addition to common compounds (Si, Fe, Al, alkalis) also elevated contents of P and Ca. The microstructure of the studied slag as well as chemistry of individual phases are very homogeneous across the whole sample. We interpret this slag as an iron smelting slag, originated during production of iron from ores using the direct method. The used ore was in all probability a limonite bog ore, whereas the use of local fresh and/or weathered pelosiderites is not probable on the basis of the recorded phase composition and chemical compositions of individual phases.
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来源期刊
Bulletin Mineralogie Petrologie
Bulletin Mineralogie Petrologie Earth and Planetary Sciences-Economic Geology
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发文量
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期刊介绍: Bulletin Mineralogie Petrologie is a peer-reviewed journal focused especially on: mineralogy, crystal chemistry and study of crystal structures of minerals study of mineral associations and processes of their origin meteoritics, research of tectites economic geology (of ore deposits) and study of history of mining of ore deposits topographic mineralogy petrology of igneous, metamorphic and sedimentary rocks instrumental analytical methods at mineralogy and petrology mineralogy and petrology as tools for archeology and similar disciplines
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