高耐化学性自流平砂浆用碱活化粘结剂

H. Funke, S. Gelbrich, L. Kroll
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引用次数: 6

摘要

本文报道了碱活化粘结剂(AAB)的研制,重点介绍了碱活化粘结剂基体的性能和耐久性。为制备基体,采用活性组分粒状矿渣和粉煤灰,用氢氧化钠(2 ~ 10 mol/l)和水玻璃水溶液(SiO2/Na2O摩尔比为2.1)在常温下进行碱活化。在氢氧化钠浓度为5.5 mol/l时,AAB凝固时间与机械强度之间的最佳折衷。在此氢氧化钠浓度下,硬化后的AAB抗压强度为53.4 MPa, 3点弯曲抗拉强度为5.5 MPa。研究结果表明,与普通硅酸盐水泥混凝土相比,aab -基质具有非常高的耐酸性能。经28次冻融循环(暴露等级:XF3)后,AAB的相对动态e模量为93%,结垢量为30 g/m2,具有较高的抗冻性,通过毛细管吸力、内部损伤和冻融试验验证了其抗冻性。
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An Alkali Activated Binder for High Chemical Resistant Self-Leveling Mortar
This paper reports the development of an Alkali Activated Binder (AAB) with an emphasis on the performance and the durability of the AAB-matrix. For the development of the matrix, the reactive components granulated slag and coal fly ash were used, which were alkali activated with a mixture of sodium hydroxide (2 - 10 mol/l) and aqueous sodium silicate solution (SiO2/Na2O molar ratio: 2.1) at ambient temperature. A sodium hydroxide concentration of 5.5 mol/l revealed the best compromise between setting time and mechanical strengths of the AAB. With this sodium hydroxide concentration, the compressive and the 3-point bending tensile strength of the hardened AAB were 53.4 and 5.5 MPa respectively after 14 days. As a result of the investigation of the acid resistance, the AAB-matrix showed a very high acid resistance in comparison to ordinary Portland cement concrete. In addition, the AAB had a high frost resistance, which had been validated by the capillary suction, internal damage and freeze thaw test with a relative dynamic E-Modulus of 93% and a total amount of scaled material of 30 g/m2 after 28 freeze-thaw cycles (exposure class: XF3).
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来源期刊
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