钨惰性气体法制备工业纯钛表面Al-Ti-N复合涂层

M. Tavoosi
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摘要

本工作旨在通过开发Ti- al - n金属间化合物复合涂层来改变纯Ti的表面性能。为此,以Al 1100为填充棒,Ar和Ar+ n2为保护气体,进行了钨惰性气体(TIG)包覆工艺。采用x射线衍射(XRD)、光学显微镜(OM)和扫描电镜(SEM)研究了样品的物相和结构。分别用维氏显微硬度计和恒电位器比较了镀层的硬度值和腐蚀行为。结果表明,在纯Ti表面可形成含有Al - 3ti、Ti - 3al - 2n2和Ti - 3al金属间化合物的复合结构。纯氩保护下焊接时,钛涂层界面处脆性相和焊接缺陷数量最少。尽管在Ar+ n2屏蔽下制备的涂层孔隙度和不均匀性等结构缺陷增加,但与Ar屏蔽下制备的涂层相比,制备的涂层具有更高的硬度(大于100 HV)和耐腐蚀性(大于2倍)。
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Development of Al-Ti-N Composite Coatings on Commercially Pure Ti Surface by Tungsten Inert Gas Process
: The present work aims to modify surface properties of pure Ti by development of Ti-Al-N intermetallic composite coatings. In this regard, tungsten inert gas (TIG) cladding process was carried out using Al 1100 as filler rod with Ar and Ar+N 2 as shielding gases. Phase and structure of the samples were investigated by X-ray diffraction (XRD) technique, optical microscopy (OM) and scanning electron microscopy (SEM). Hardness values and corrosion behavior of the obtained coatings were also compared using Vickers microhardness tester and potentiostat, respectively. The results showed that composite structure containing Al 3 Ti, Ti 3 Al 2 N 2 and Ti 3 Al intermetallic compounds could be formed on the surface of pure Ti. Amounts of brittle phases and welding defects at the titanium-coating interface were least by welding under pure Ar shielding. Despite the increasing amount of structural defects such as porosity and non-uniformity under Ar+N 2 shielding, the prepared coatings had higher hardness (more than 100 HV) and corrosion resistance (more than twice) compared with those obtained under Ar shielding.
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