利用化学和生物机械方法高效制造纳米纤维素的研究进展

A. Bharimalla, S. Deshmukh, P. G. Patil, N. Vigneshwaran
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引用次数: 55

摘要

纳米纤维素是一种从纤维素生物质中提取的新型材料,具有比表面积大、模量高、亲水性强等特点。它包括两种结构形式,即纳米纤维化纤维素(NFC)和纳米晶体纤维素(NCC)。本文综述了近年来生产纳米纤维素的生物和化学机械工艺方法,它们的能量需求和功能特性。十几个试验工厂/商业工厂大多在发达国家运作,试图开发纳米纤维素作为纸张、薄膜、混凝土、橡胶、聚合物薄膜等增强剂的潜力。纳米纤维素的利用主要受到初期投资、生产成本高和缺乏毒理学信息的限制。本文综述了利用化学和生物两种方法进行预处理的节能环保机械方法的发展趋势和探索,其规模化的可行性以及纳米纤维素在不影响环境的情况下在各个领域的应用前景。此外,还推导了纳米纤维素质量指标,作为基于应用筛选纳米纤维素生产方案的指南。
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Energy Efficient Manufacturing of Nanocellulose by Chemo- and Bio-Mechanical Processes: A Review
Nanocellulose is a new-age material derived from cellulosic biomass and has large specific surface area, high modulus and highly hydrophilic in nature. It comprises of two structural forms viz., nanofibrillated cellulose (NFC) and nanocrystalline cellulose (NCC). This review provides a critical overview of the recent methods of bio- and chemo-mechanical processes for production of nanocellulose, their energy requirements and their functional properties. More than a dozen of pilot plants/commercial plants are under operation mostly in the developed countries, trying to exploit the potential of nanocellulose as reinforcing agent in paper, films, concrete, rubber, polymer films and so on. The utilization of nanocellulose is restricted mainly due to initial investment involved, high production cost and lack of toxicological information. This review focuses on the current trend and exploration of energy efficient and environment-friendly mechanical methods using pretreatments (both chemical and biological), their feasibility in scaling up and the future scope for expansion of nanocellulose application in diverse fields without impacting the environment. In addition, a nanocellulose quality index is derived to act as a guide for application based screening of nanocellulose production protocols.
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