{"title":"部分封闭电极上不可逆电氧化的模拟","authors":"M. Lovrić, Š. Komorsky-Lovrić","doi":"10.4152/pea.202003165","DOIUrl":null,"url":null,"abstract":"An irreversible electrode reaction influenced by the reversible potential dependent inhibition is theoretically analysed. The consequence of reactivation of the electrode surface is the continuation of electro-oxidation and the appearance of the second anodic peak in cyclic voltammetry. An indicator of the change of the electrode kinetics caused by the inhibitor is proposed.","PeriodicalId":1,"journal":{"name":"Accounts of Chemical Research","volume":null,"pages":null},"PeriodicalIF":16.4000,"publicationDate":"2020-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":"{\"title\":\"Simulation of Irreversible Electro-oxidation on a Partially Blocked Electrode\",\"authors\":\"M. Lovrić, Š. Komorsky-Lovrić\",\"doi\":\"10.4152/pea.202003165\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"An irreversible electrode reaction influenced by the reversible potential dependent inhibition is theoretically analysed. The consequence of reactivation of the electrode surface is the continuation of electro-oxidation and the appearance of the second anodic peak in cyclic voltammetry. An indicator of the change of the electrode kinetics caused by the inhibitor is proposed.\",\"PeriodicalId\":1,\"journal\":{\"name\":\"Accounts of Chemical Research\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":16.4000,\"publicationDate\":\"2020-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Accounts of Chemical Research\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.4152/pea.202003165\",\"RegionNum\":1,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Accounts of Chemical Research","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.4152/pea.202003165","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
Simulation of Irreversible Electro-oxidation on a Partially Blocked Electrode
An irreversible electrode reaction influenced by the reversible potential dependent inhibition is theoretically analysed. The consequence of reactivation of the electrode surface is the continuation of electro-oxidation and the appearance of the second anodic peak in cyclic voltammetry. An indicator of the change of the electrode kinetics caused by the inhibitor is proposed.
期刊介绍：
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
