摩洛哥野生黄连木叶片提取物在3% NaCl溶液中对铁腐蚀绿的抑制作用

IF 16.4 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Accounts of Chemical Research Pub Date : 2020-01-01 DOI:10.4152/pea.202003175
Mohammed Barbouchi, B. Benzidia, M. E. Idrissi, M. Choukrad
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引用次数: 3

摘要

本文采用气相色谱-质谱联用技术对黄连木(Pistacia terebinthus L., PT)叶片甲醇提取物进行了表征。通过重量测量和电化学方法(动电位极化和电化学阻抗谱),在3% NaCl溶液中测试了它作为铁的缓蚀剂。鉴定出14个化合物;主要化合物为棕榈酸(31.5%)、硬脂酸(25.7%)和油酸(11.3%)。实验结果表明,该萃取物具有良好的耐蚀性。PT萃取物的成分影响极化电阻(Rp)和腐蚀电流密度(icorr),表明所提出的缓蚀剂阻碍了腐蚀反应。在200 ppm下得到的结果非常有趣,分别达到96.96%、89%和64.82%的最大值,通过扫描电镜(SEM)和x射线能谱(EDX)验证了这一结果。
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Iron Corrosion Green Inhibition in a 3% NaCl Solution, by Leaves Extract from Pistacia Terebinthus L. Growing Wild in Morocco
In the present paper, the methanol extract from the leaves of Pistacia terebinthus L. (PT) was characterized by GC/MS analysis. It was tested as a corrosion inhibitor for iron in a 3% NaCl solution, using gravimetric measurements and electrochemical methods (potentiodynamic polarizations and electrochemical impedance spectroscopy). Fourteen compounds were identified; the major compounds are palmitic acid (31.5%), stearic acid (25.7%) and oleic acid (11.3%). The data showed that the tested extract offers good corrosion resistance. The constituents of the PT extract affected polarization resistance (Rp) and corrosion current density (icorr), demonstrating that the proposed inhibitor hinders corrosion reactions. The results obtained at 200 ppm are very interesting, and reach maximum values of 96.96%, 89% and 64.82%, respectively, which were confirmed by scanning electron microscopy (SEM), coupled with energy scattering of X-ray spectroscopy (EDX).
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来源期刊
Accounts of Chemical Research
Accounts of Chemical Research 化学-化学综合
CiteScore
31.40
自引率
1.10%
发文量
312
审稿时长
2 months
期刊介绍: Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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