A. Yagodin, A. Martynov, Yulia G. Gorbunova, A. Tsivadze
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Benzoannelated A3B-Phthalocyanines with Diethyleneglycol Substituents: Synthesis and Control of Aggregation
New benzoannelated phthalocyanine H 2 A 3 B has been synthesized by cross-condensation of 4,5-dibutoxyphthalonitrile A and naphthalonitrile B bearing two diethyleneglycol substituents. UV-Vis and 1 H NMR measurements performed for H 2 A 3 B showed that the presence of free OH-groups in H 2 A 3 B enhances its aggregation in solution in comparison with its O-tetrahydropyranyl derivative H 2 A 3 Bt , which can be considered as a way to control the physicochemical properties of asymmetric phthalocyanines.
期刊介绍：
The journal is a forum for the specialists investigating macroheterocyclic compounds. It publishes original experimental and theoretical works (full papers and short communications) and reviews on synthesis, structural characterization, physical and coordination chemistry as well as practical application of macroheterocycles.
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