去卟啉IX及其二甲酯与低聚乙二醇的相互作用

IF 1 4区化学 Q4 CHEMISTRY, MULTIDISCIPLINARY Macroheterocycles Pub Date : 2022-01-01 DOI:10.6060/mhc213705r

T. K. Rocheva, D. V. Belykh

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引用次数: 0

摘要

研究了去卟啉IX羧基的酯化反应和去卟啉IX二甲酯酯基与二、四、六乙二醇的酯交换反应。结果表明，根据低聚乙二醇和反应条件的不同，既可以得到分子中含有两个聚酯基团(每个丙酸取代基一个)的衍生物，也可以得到含有一个聚酯基团连接卟啉丙酸取代基的衍生物。

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The Interaction of Deuteroporphyrin IX and its Dimethyl Ester with Oligoethylene Glycols

The esterification of carboxyl groups of deuteroporphyrin IX and transesterification of ester groups of dimethyl ester of deuteroporphyrin IX with di-, tetra-, hexaethylene glycols were studied. It is shown, that depending on the oligoethylene glycol and the reaction conditions used, both derivatives with two polyester moieties in the molecule (one for each propionate substituent) and derivatives with one polyester moiety linking the propionate substituents of por-phyrin can be obtained.

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来源期刊

Macroheterocycles CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

2.30

自引率

21.40%

发文量

期刊介绍： The journal is a forum for the specialists investigating macroheterocyclic compounds. It publishes original experimental and theoretical works (full papers and short communications) and reviews on synthesis, structural characterization, physical and coordination chemistry as well as practical application of macroheterocycles.