N. V. Tverdova, N. Giricheva, V. Maizlish, N. Galanin, G. V. Girichev
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From Сonformational Properties of 4-(4-Tritylphenoxy)phthalonitrile Precursor to Conformational Properties of Substituted Phthalocyanines
The conformational properties and structure of the conformers of 4-(4-tritylphenoxy)phthalonitrile (C 33 H 22 N 2 O), acting as a precursor for the synthesis of tritylphenoxy substituted phthalocyanines, were investigated by DFT method. The conformational analysis of the C 33 H 22 N 2 O molecule indicates the possibility of formation of conformers of substituted phthalocyanines with different orientations of 4-tritylphenoxy substituents, including those with a combination of cis- and trans- positions within one complex.
期刊介绍：
The journal is a forum for the specialists investigating macroheterocyclic compounds. It publishes original experimental and theoretical works (full papers and short communications) and reviews on synthesis, structural characterization, physical and coordination chemistry as well as practical application of macroheterocycles.
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