{"title":"使用氧化石墨烯的自热砂浆,随着直流电的应用增加了CSH凝胶的形成","authors":"İsmail Hocaoğlu","doi":"10.7764/rdlc.20.3.559","DOIUrl":null,"url":null,"abstract":"Graphene oxide (GO) is that the product of the exfoliation of graphite by chemical processes. GO has a potential candidate to be used as a nano reinforcement material in cement-based systems due to its water dispensability, quite good mechanical properties, and high aspect ratios. In this research, the effects of different water/binder (water/cement) ratio (0.55, 0.70, 0.90, and 1.00) and graphene oxide on mortars to which applied DC stress intensity have been investigated. In experiments, 4cm x 4cm x 16cm wood molds (electrical isolated) have been used. Immediately after mixing into the mixtures, a stress intensity of 25 V was applied for 24 hours with a DC power source. Experiments were conducted in the laboratory conditions. Effect on hydration internal temperatures of the mortars with direct current application has been investigated. It is also researched that, the effect of graphene oxide on hydration temperature by direct current (DC) application on mortars. Through the application of 25 V DC to the 300 dosage mortars to which have different w/c ratios (0.55, 0.70, 0.90 and 1.00), their internal temperatures are increased as 1.26 °C, 1.78 °C, 4.25, and 3.30 °C, respectively. When they are compared to the same water/cement ratio of reference samples, it has been observed that, when 0.025 % ratio of graphene oxide has been added to admixture and also direct current has applied, hydration temperature values of mortars have been increased. Microscope views have been investigated from 300 dosage mortars whose w/c ratio is 0.90 and it is determined that CSH gel formation increases as using 0.025 % GO and DC stress intensity application. 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引用次数: 1
摘要
氧化石墨烯(GO)是石墨在化学过程中剥落的产物。由于氧化石墨烯的可疏水性、良好的机械性能和高纵横比,它有可能被用作水泥基体系中的纳米增强材料。在本研究中,研究了不同水/胶料(水/水泥)比(0.55、0.70、0.90和1.00)和氧化石墨烯对施加直流应力强度砂浆的影响。在实验中,使用了4cm × 4cm × 16cm的木模(电隔离)。混合后立即在直流电源上施加25 V的应力强度24小时。实验在实验室条件下进行。研究了直流电对砂浆水化内部温度的影响。研究了直流作用下氧化石墨烯对砂浆水化温度的影响。对w/c比分别为0.55、0.70、0.90和1.00的300种掺量砂浆施加25 V DC,使其内部温度分别升高1.26℃、1.78℃、4.25℃和3.30℃。将其与相同水灰比的参考样品进行比较,发现在掺合料中加入0.025%的氧化石墨烯并施加直流电时,砂浆的水化温量值有所提高。对w/c比为0.90的300种剂量砂浆进行了显微镜观察,结果表明,使用0.025%的氧化石墨烯和施加直流应力强度时,CSH凝胶形成增加。通过对砂浆施加电流并在混合物中加入氧化石墨烯,可以加速水化反应。
Self-heating mortars with using graphene oxide and increasing CSH gel formation with the direct current application
Graphene oxide (GO) is that the product of the exfoliation of graphite by chemical processes. GO has a potential candidate to be used as a nano reinforcement material in cement-based systems due to its water dispensability, quite good mechanical properties, and high aspect ratios. In this research, the effects of different water/binder (water/cement) ratio (0.55, 0.70, 0.90, and 1.00) and graphene oxide on mortars to which applied DC stress intensity have been investigated. In experiments, 4cm x 4cm x 16cm wood molds (electrical isolated) have been used. Immediately after mixing into the mixtures, a stress intensity of 25 V was applied for 24 hours with a DC power source. Experiments were conducted in the laboratory conditions. Effect on hydration internal temperatures of the mortars with direct current application has been investigated. It is also researched that, the effect of graphene oxide on hydration temperature by direct current (DC) application on mortars. Through the application of 25 V DC to the 300 dosage mortars to which have different w/c ratios (0.55, 0.70, 0.90 and 1.00), their internal temperatures are increased as 1.26 °C, 1.78 °C, 4.25, and 3.30 °C, respectively. When they are compared to the same water/cement ratio of reference samples, it has been observed that, when 0.025 % ratio of graphene oxide has been added to admixture and also direct current has applied, hydration temperature values of mortars have been increased. Microscope views have been investigated from 300 dosage mortars whose w/c ratio is 0.90 and it is determined that CSH gel formation increases as using 0.025 % GO and DC stress intensity application. It is concluded that hydration reactions can be accelerated by applying electric current to the mortar and adding graphene oxide to the mixture.
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