扩展阴离子C-甲基杯[4]间苯二酚芳烃无机骨架中的阳离子客体

Philip O. Brown , Gary D. Enright , John A. Ripmeester
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引用次数: 15

摘要

在酸性条件下,在适当的无机离子存在下,联吡啶型分子将与C-甲基杯[4]间苯二酚烯自组装,产生主客体超分子结构,其中间苯二酚烯采用开舟构象,间苯二酚烯链由无机离子连接,以及作为客体包含的不与宿主特异性相互作用的联吡啶鎓型分子。
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Cationic guests in extended anionic C-methylcalix[4]resorcinarene-inorganic frameworks

Under acidic conditions and in the presence of appropriate inorganic ions, bipyridyl-type molecules will self-assemble with C-methylcalix[4]resorcinarene to yield a host–guest supramolecular structure in which the resorcinarene adopts the open boat conformation, with the resorcinarene chains linked by the inorganic ions, and bipyridinium-type molecules included as guests that do not interact specifically with the host.

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