乙二胺和乙酸根离子浓度对Cu(111)/Pb+2体系中欠电位效应发生的影响

A. Budniok, J. Baranska
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引用次数: 1

摘要

铅对铜的欠电位效应的发生取决于溶液中乙二胺和乙酸根离子的浓度以及溶液pH。欠电位效应发生强度变化的原因是Cu(111)/Pb+2+CH3 COO−+乙二胺+H+体系化学稳定性的变化。
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The influence of concentration of ethylenediamine and acetate ions on the occurrence of underpotential effects in the system Cu(111)/Pb+2

The occurrence of lead on copper underpotential effects is dependent on concentration of ethylenediamine and acetate ions in the solution and also on solution pH. The cause of variations in intensity of occurrence of underpotential effects is the change in the state of chemical stability of the system Cu(111)/Pb+2 + CH3 COO + ethylenediamine + H+.

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