{"title":"乙二胺和乙酸根离子浓度对Cu(111)/Pb+2体系中欠电位效应发生的影响","authors":"A. Budniok, J. Baranska","doi":"10.1016/0390-6035(82)90066-9","DOIUrl":null,"url":null,"abstract":"<div><p>The occurrence of lead on copper underpotential effects is dependent on concentration of ethylenediamine and acetate ions in the solution and also on solution pH. The cause of variations in intensity of occurrence of underpotential effects is the change in the state of chemical stability of the system Cu(111)/Pb<sup>+2</sup> + CH<sub>3</sub> COO<sup>−</sup> + ethylenediamine + H<sup>+</sup>.</p></div>","PeriodicalId":18221,"journal":{"name":"Materials Chemistry","volume":"7 5","pages":"Pages 629-637"},"PeriodicalIF":0.0000,"publicationDate":"1982-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0390-6035(82)90066-9","citationCount":"1","resultStr":"{\"title\":\"The influence of concentration of ethylenediamine and acetate ions on the occurrence of underpotential effects in the system Cu(111)/Pb+2\",\"authors\":\"A. Budniok, J. Baranska\",\"doi\":\"10.1016/0390-6035(82)90066-9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The occurrence of lead on copper underpotential effects is dependent on concentration of ethylenediamine and acetate ions in the solution and also on solution pH. The cause of variations in intensity of occurrence of underpotential effects is the change in the state of chemical stability of the system Cu(111)/Pb<sup>+2</sup> + CH<sub>3</sub> COO<sup>−</sup> + ethylenediamine + H<sup>+</sup>.</p></div>\",\"PeriodicalId\":18221,\"journal\":{\"name\":\"Materials Chemistry\",\"volume\":\"7 5\",\"pages\":\"Pages 629-637\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1982-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0390-6035(82)90066-9\",\"citationCount\":\"1\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0390603582900669\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0390603582900669","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The influence of concentration of ethylenediamine and acetate ions on the occurrence of underpotential effects in the system Cu(111)/Pb+2
The occurrence of lead on copper underpotential effects is dependent on concentration of ethylenediamine and acetate ions in the solution and also on solution pH. The cause of variations in intensity of occurrence of underpotential effects is the change in the state of chemical stability of the system Cu(111)/Pb+2 + CH3 COO− + ethylenediamine + H+.