{"title":"异羟肟酸化学XII:N-苯基苯甲酰胺酸的光化学反应机理研究","authors":"Ewa Lipczyńska-kochany, Jan Kochany","doi":"10.1016/0047-2670(87)87028-4","DOIUrl":null,"url":null,"abstract":"<div><p>The quantum yield for the photodestruction of <em>N</em>-phenylbenzenecarbohydroxamic acid was determined in a number of solvents. Protonation was found to photostabilize both the hydroxamic acid and its anion. Quenching studies showed that the reaction in cyclohexane occurs from both the singlet and the triplet state, giving benzanilide as the main photoproduct. The results are discussed in the light of other recent investigations in the field.</p></div>","PeriodicalId":16771,"journal":{"name":"Journal of Photochemistry","volume":"38 ","pages":"Pages 331-343"},"PeriodicalIF":0.0000,"publicationDate":"1987-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0047-2670(87)87028-4","citationCount":"12","resultStr":"{\"title\":\"Chemistry of hydroxamic acid XII: Photochemistry of N-phenylbenzenecarbo-hydroxamic acid—studies on the mechanism of reaction\",\"authors\":\"Ewa Lipczyńska-kochany, Jan Kochany\",\"doi\":\"10.1016/0047-2670(87)87028-4\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The quantum yield for the photodestruction of <em>N</em>-phenylbenzenecarbohydroxamic acid was determined in a number of solvents. Protonation was found to photostabilize both the hydroxamic acid and its anion. Quenching studies showed that the reaction in cyclohexane occurs from both the singlet and the triplet state, giving benzanilide as the main photoproduct. The results are discussed in the light of other recent investigations in the field.</p></div>\",\"PeriodicalId\":16771,\"journal\":{\"name\":\"Journal of Photochemistry\",\"volume\":\"38 \",\"pages\":\"Pages 331-343\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1987-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0047-2670(87)87028-4\",\"citationCount\":\"12\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Photochemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0047267087870284\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Photochemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0047267087870284","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Chemistry of hydroxamic acid XII: Photochemistry of N-phenylbenzenecarbo-hydroxamic acid—studies on the mechanism of reaction
The quantum yield for the photodestruction of N-phenylbenzenecarbohydroxamic acid was determined in a number of solvents. Protonation was found to photostabilize both the hydroxamic acid and its anion. Quenching studies showed that the reaction in cyclohexane occurs from both the singlet and the triplet state, giving benzanilide as the main photoproduct. The results are discussed in the light of other recent investigations in the field.
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