Satyam Singh, R. Yadav, P. Pande, T. W. Kim, Ashutosh Kumar Singh, Chandani Singh, Jin‐Ook Baeg
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Photocatalytic turnover number & turnover frequency of 4-HNB under solar light by ‘1’ photocatalyst with & without reducer
4-hydroxynitrobenzene (4-HNB) is a highly effective industrial pollutant that causes adverse effects to human beings. In this regard, detoxification of noxious water is utmost indispensable. Highly efficient metal-free photocatalytic degradation and reduction of 4-HNB with and without reducing agent still challenge. Additionally, for this role, largely expensive reagents that can create inauspicious impacts on the environment are utilized. Herein, we developed a ‘1’ photocatalyst that has the excellent ability for the H2O2-mediated degradation and reductant-free reduction of 4-HNB. The ‘1’ photocatalyst has an excellent turnover number (TON) 0.644×1020 molecules and turnover frequency (TOF) 0.0035×1020 molecules /min.
期刊介绍:
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.