利用激光染料荧光最大位移检测有机化合物的技术

J. Dadge, D. Thakur
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引用次数: 0

摘要

提出了一种可用于检测有机化合物的技术。在乙醇中溶解罗丹明- 6g(一种激光染料),得到罗丹明- 6g浓度为0.005 m的罗丹明-乙醇(Rh-Eth)溶液,在Rh-Eth溶液中加入0.25 cm3的甲醇,用氮气激光泵送得到的Rh-Eth- me溶液。与不含甲醇的Rh-Eth溶液相比,在Rh-Eth- me的荧光光谱中观察到蓝移。当分别加入丙酮和乙腈时,在Rh-Eth溶液中也观察到类似的蓝移。将罗丹明- 6g和香豆素460与聚甲基丙烯酸甲酯(PMMA)一起添加到乙醇中,与不添加PMMA的乙醇中的Rh-6G和Cou460相比,荧光光谱出现了蓝移。荧光光谱中的光谱移位现象可用于检测有机化合物,并讨论了其机理。
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A Technique for Sensing Organic Compounds Using Fluorescence Maximum Shift In Laser Dyes
A technique that could be used for sensing organic compounds is presented. In ethanol, Rhodamine-6G (a laser dye) was dissolved to obtain a Rhodamine-ethanol (Rh-Eth) solution with the concentration of Rhodamine-6G being 0.005 M. Methanol (0.25 cm3) was added to the Rh-Eth solution and the Rh-Eth-Me solution so obtained was pumped with a nitrogen laser. A blue shift in the fluorescence spectrum of the Rh-Eth-Me was observed as compared to the Rh-Eth solution without methanol. A similar blue shift was observed in the Rh-Eth solution when acetone and acetonitrile were separately added. When Rhodamine-6G and Coumarin460 were added with Polymethyl methacrylate (PMMA) in ethanol, a blue shift was observed in the fluorescence spectrum as compared to the Rh-6G and Cou460 in ethanol without PMMA. The phenomena of spectral shifts in the fluorescence spectrum can be used to sense organic compounds and a mechanism is discussed.
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