S. Imamaliyeva, D. Babanly, V. Zlomanov, M. Babanly, D. Taghiyev
{"title":"碲化铽的热力学性质","authors":"S. Imamaliyeva, D. Babanly, V. Zlomanov, M. Babanly, D. Taghiyev","doi":"10.17308/kcmf.2020.22/3116","DOIUrl":null,"url":null,"abstract":"The paper presents the results of a study of solid-phase equilibria in the Tb–Te system and the thermodynamic properties of terbium tellurides obtained by the methods of electromotive forces and X-ray diffraction analysis. Based on the experimental data, it was established that the TbTe, Tb2Te3, TbTe2 и TbTe3 compounds are formed in the system. For the investigations of the alloys from the two-phase regions TbTe3+Te, TbTe2+TbTe3, and Tb2Te3+TbTe2, the EMF of concentration cells relative to the TbTe electrode was measured. The EMF of concentration cells relative to the terbium electrode was measured for the TbTe+Tb2T3 region. The partial thermodynamic functions of TbTe and Tb in alloys were determined bycombining the EMF measurements of both types in the 300–450 K temperature range, based on which the standard thermodynamic functions of formation and standard entropies of the indicated terbium tellurides were calculated. \n \n \n \nReferences1. Jha A. R. Rare earth materials: properties andapplications. United States. CRC Press. 2014. 371 p.DOI: https://doi.org/10.1201/b170452. Balaram V. Rare earth elements: A review ofapplications, occurrence, exploration, analysis,recycling, and environmental impact. GeoscienceFrontiers. 2019;10(4): 1285–1290. DOI: https://doi.org/10.1016/j.gsf.2018.12.0053. Yarembash E. I., Eliseev A. A. Khal’kogenidyredkozemel’nykh elementov [Chalcogenides of rareearth elements). Moscow: Nauka Publ.; 1975. 258p.(In Russ.)4. Y-Sc., La-Lu. Gmelin Handbock of InorganicChemistry. In: Hartmut Bergmann (Ed.), Rare EarthElements, 8th Edition, Springer-Verlag HeidelbergGmbH. Berlin; 1987.5. Muthuselvam I. P., Nehru R., Babu K. R.,Saranya K., Kaul S. N., Chen S-M, Chen W-T, Liu Y.,Guo G-Y, Xiu F., Sankar R. Gd2Te3 an antiferromagneticsemimetal. J. Condens. Matter Phys. 2019;31(28):285802-5. DOI: https://doi.org/10.1088/1361-648X/ab15706. Huang H., Zhu J.-J. The electrochemicalapplications of rare earth-based nanomaterials.Analyst. 2019;144(23): 6789–6811. DOI: https://doi.org/10.1039/C9AN01562K7. Saint-Paul M., Monceau P. Survey of thethermodynamic properties of the charge density wavesystems. Adv. Cond. Matter Phys. 2019: 1–5 DOI:https://doi.org/10.1155/2019/21382648. Cheikh D., Hogan B. E., Vo T., Allmen P. V., Lee K.,Smiadak D. M., Zevalkink A., Dunn B. S., Fleurial J-P.,Bux S. L. Praseodymium telluride: A high temperature,high- ZT thermoelectric material. Joule. 2018; 2(4):698–709. DOI: https://doi.org/10.1016/j.joule.2018.01.0139. Patil S. J., Lokhande A. C., Lee D. W, Kim J. H.,Lokhande C. D. Chemical synthesis and supercapacitiveproperties of lanthanum telluride thin film. Journal ofColloid and Interface Science. 2017; 490: 147–153. DOI:https://doi.org/10.1016/j.jcis.2016.11.02010. Zhou X. Z., Zhng K. H. L, Xiog J., Park J-H,Dickerson J-H., He W. Size- and dimentionalitydependent optical, mahnetic and magneto-opticalproperties of binary europium-based nanocrystals:EuX (X=O, S, Se, Te). Nanotechnology. 2016;27(19):192001-5. DOI: https://doi.org/10.1088/0957-4484/27/19/19200111. Okamoto H. Desk handbook phase diagram forbinary alloys. ASM International. 2000. 900 p.12. Babanly M. B., Mashadiyeva L. F., Babanly D. M.,Imamaliyeva S. Z., Tagiyev D. B., Yusibov Y. A.. Someissues of complex studies of phase equilibria andthermodynamic properties in ternary chalcogenidesystems involving Emf measurements. Russian Journalof Inorganic Chemistry. 2019;64(13): 1649–1672. DOI:https://doi.org/10.1134/s003602361913003513. Imamaliyeva S. Z., Babanly D. M., Tagiev D. B.,Babanly M. B. Physicochemical aspects of developmentof multicomponent chalcogenide phases having theTl5Te3 structure. A review. Russian Journal of InorganicChemistry2018;63(13): 1703–1724 DOI: https://doi.org/10.1134/s003602361813004114. Massalski T. B. Binary alloys phase diagrams,second edition. ASM International, Materials Park.Ohio; 1990. 3835 p. DOI: https://doi.org/10.1002/adma.1991003121515. Diagrammi sostoyaniya dvoynikh metallicheskikhsystem [Diagrams of Binary Metallic Systems]Handbook in 3 vols. Lyakishev N.P. (Ed.) Moscow:Mashinostroenie Publ.; 1996, 1997, 2001. (In Russ.)16. Eliseev A. A., Orlova I. G., Martynova L. F.,Pechennikov A. V., Chechernikov V. I. Paramagnetismof some terbium chalcogenides. Inorganic Materials.1987;23: 1833–1835.17. Mills K. C. Thermodynamic data for inorganicsulphides, selenides, and tellurides. London:Butterworth; 1974. 854 p.18. Vassiliev V. P., Lysenko V. A. Gaune-Escard M.Relationship of thermodynamic data with periodic law.Pure and Applied Chemistry. 2019;91(6): 879–884. DOI:https://doi.org/10.1515/pac-2018-071719. Vassiliev V. P., Lysenko V. A. New approach forthe study of thermodynamic properties of lanthanidecompounds. Electrochimica Acta. 2016;222: 1770–1775.DOI: https://doi.org/10.1016/j.electacta.2016.11.07520. Morachevsky A. G., Voronin G. F., Geyderich V. A.,Kutsenok I. B. Elektrokhimicheskie metody issledovaniyav t e r m o d i n a m i k e m e t a l l i c h e s k i k h s y s t e m .[Electrochemical methods of investigation inhermodynamics of metal systems]. Moscow:Akademkniga Publ.; 2003. 334 p. Available at: https://elibrary.ru/item.asp?id=19603291 (In Russ.)21. Babanly M. B., Yusibov Y. A. Elektrokhimicheskiemetody v termodinamike neorganicheskikh sistem[Electrochemical methods in thermodynamics ofinorganic systems]. Baku: BSU Publ.; 2011. 306 p.22. Imamaliyeva S. Z., Mehdiyeva I. F., Taghiyev D. B.et al. Thermodynamic investigations of the erbiumtellurides by EMF method. Physics and Chemistry ofSolid State. 2020;21(2): 312–318. DOI: https://doi.org/10.15330/pcss.21.2.312-31823. Hasanova G. S., Aghazade A. I., Yusibov Yu. A.,Babanly M. B. Thermodynamic investigation of theBi2Se3-Bi2Te3 system by the EMF method. Kondensirovannyesredy i mezhfaznye granitsy = CondensedMatter and Interphases. 2020;22(3): 310–319. DOI:https://doi.org/10.17308/kcmf.2020.22/296124. Imamaliyeva S. Z., Babanly D. M., Gasanly T. M.,et al.: Thermodynamic properties of Tl9GdTe6 andTlGdTe2. Russian Journal of Physical Chemistry A.2018;92(11): 2111–2116. DOI: https://doi.org/10.1134/s003602441811015825. Mansimova S. H., Orujlu E. N., Sultanova S. G.,Babanly M. B. Thermodynamic properties of Pb6Sb6Se17.Kondensirovannye sredy i mezhfaznye granitsy =Condensed Matter and Interphases. 2017;19(4): 536–541. https://doi.org/10.17308/kcmf.2017.19/23426. Imamaliyeva S. Z., Gasanly T. M., MahmudovaM. A. Thermodynamic properties of GdTe compound.Physics. 2017;22: 19–21. Available at: http://physics.gov.az/Dom/2017/AJP_Fizika_04_2017_en.pdf27. Imamaliyeva S. Z., Musayeva S. S., Babanly D. M.,Jafarov Y. I., Tagiyev D. B., Babanly M. B. Determinationof the thermodynamic functions of bismuthchalcoiodides by EMF method with morpholiniumformate as electrolyte. Thermochim. Acta. 2019; 679:178319–17825. DOI: https://doi.org/10.1016/j.tca.2019.17831928. Baza dannykh termicheskikh konstant veshchestv.Elektronnaya versiya pod. red. V. S. Yungmana. 2006[Database of thermal constants of substances.Electronic version V. S. Yungman (ed.). 2006]. Availableat: http://www.chem.msu.ru/cgi-bin/tkv.pl?show=welcome.html/welcome.html","PeriodicalId":17879,"journal":{"name":"Kondensirovannye sredy i mezhfaznye granitsy = Condensed Matter and Interphases","volume":"73 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2020-12-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Thermodynamic Properties of Terbium Tellurides\",\"authors\":\"S. Imamaliyeva, D. Babanly, V. Zlomanov, M. Babanly, D. Taghiyev\",\"doi\":\"10.17308/kcmf.2020.22/3116\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The paper presents the results of a study of solid-phase equilibria in the Tb–Te system and the thermodynamic properties of terbium tellurides obtained by the methods of electromotive forces and X-ray diffraction analysis. Based on the experimental data, it was established that the TbTe, Tb2Te3, TbTe2 и TbTe3 compounds are formed in the system. For the investigations of the alloys from the two-phase regions TbTe3+Te, TbTe2+TbTe3, and Tb2Te3+TbTe2, the EMF of concentration cells relative to the TbTe electrode was measured. The EMF of concentration cells relative to the terbium electrode was measured for the TbTe+Tb2T3 region. The partial thermodynamic functions of TbTe and Tb in alloys were determined bycombining the EMF measurements of both types in the 300–450 K temperature range, based on which the standard thermodynamic functions of formation and standard entropies of the indicated terbium tellurides were calculated. \\n \\n \\n \\nReferences1. Jha A. R. Rare earth materials: properties andapplications. United States. CRC Press. 2014. 371 p.DOI: https://doi.org/10.1201/b170452. Balaram V. Rare earth elements: A review ofapplications, occurrence, exploration, analysis,recycling, and environmental impact. GeoscienceFrontiers. 2019;10(4): 1285–1290. DOI: https://doi.org/10.1016/j.gsf.2018.12.0053. Yarembash E. I., Eliseev A. A. Khal’kogenidyredkozemel’nykh elementov [Chalcogenides of rareearth elements). Moscow: Nauka Publ.; 1975. 258p.(In Russ.)4. Y-Sc., La-Lu. Gmelin Handbock of InorganicChemistry. In: Hartmut Bergmann (Ed.), Rare EarthElements, 8th Edition, Springer-Verlag HeidelbergGmbH. Berlin; 1987.5. Muthuselvam I. P., Nehru R., Babu K. R.,Saranya K., Kaul S. N., Chen S-M, Chen W-T, Liu Y.,Guo G-Y, Xiu F., Sankar R. Gd2Te3 an antiferromagneticsemimetal. J. Condens. Matter Phys. 2019;31(28):285802-5. DOI: https://doi.org/10.1088/1361-648X/ab15706. Huang H., Zhu J.-J. The electrochemicalapplications of rare earth-based nanomaterials.Analyst. 2019;144(23): 6789–6811. DOI: https://doi.org/10.1039/C9AN01562K7. Saint-Paul M., Monceau P. Survey of thethermodynamic properties of the charge density wavesystems. Adv. Cond. Matter Phys. 2019: 1–5 DOI:https://doi.org/10.1155/2019/21382648. Cheikh D., Hogan B. E., Vo T., Allmen P. V., Lee K.,Smiadak D. M., Zevalkink A., Dunn B. S., Fleurial J-P.,Bux S. L. Praseodymium telluride: A high temperature,high- ZT thermoelectric material. Joule. 2018; 2(4):698–709. DOI: https://doi.org/10.1016/j.joule.2018.01.0139. Patil S. J., Lokhande A. C., Lee D. W, Kim J. H.,Lokhande C. D. Chemical synthesis and supercapacitiveproperties of lanthanum telluride thin film. Journal ofColloid and Interface Science. 2017; 490: 147–153. DOI:https://doi.org/10.1016/j.jcis.2016.11.02010. Zhou X. Z., Zhng K. H. L, Xiog J., Park J-H,Dickerson J-H., He W. Size- and dimentionalitydependent optical, mahnetic and magneto-opticalproperties of binary europium-based nanocrystals:EuX (X=O, S, Se, Te). Nanotechnology. 2016;27(19):192001-5. DOI: https://doi.org/10.1088/0957-4484/27/19/19200111. Okamoto H. Desk handbook phase diagram forbinary alloys. ASM International. 2000. 900 p.12. Babanly M. B., Mashadiyeva L. F., Babanly D. M.,Imamaliyeva S. Z., Tagiyev D. B., Yusibov Y. A.. Someissues of complex studies of phase equilibria andthermodynamic properties in ternary chalcogenidesystems involving Emf measurements. Russian Journalof Inorganic Chemistry. 2019;64(13): 1649–1672. DOI:https://doi.org/10.1134/s003602361913003513. Imamaliyeva S. Z., Babanly D. M., Tagiev D. B.,Babanly M. B. Physicochemical aspects of developmentof multicomponent chalcogenide phases having theTl5Te3 structure. A review. Russian Journal of InorganicChemistry2018;63(13): 1703–1724 DOI: https://doi.org/10.1134/s003602361813004114. Massalski T. B. Binary alloys phase diagrams,second edition. ASM International, Materials Park.Ohio; 1990. 3835 p. DOI: https://doi.org/10.1002/adma.1991003121515. Diagrammi sostoyaniya dvoynikh metallicheskikhsystem [Diagrams of Binary Metallic Systems]Handbook in 3 vols. Lyakishev N.P. (Ed.) Moscow:Mashinostroenie Publ.; 1996, 1997, 2001. (In Russ.)16. Eliseev A. A., Orlova I. G., Martynova L. F.,Pechennikov A. V., Chechernikov V. I. Paramagnetismof some terbium chalcogenides. Inorganic Materials.1987;23: 1833–1835.17. Mills K. C. Thermodynamic data for inorganicsulphides, selenides, and tellurides. London:Butterworth; 1974. 854 p.18. Vassiliev V. P., Lysenko V. A. Gaune-Escard M.Relationship of thermodynamic data with periodic law.Pure and Applied Chemistry. 2019;91(6): 879–884. DOI:https://doi.org/10.1515/pac-2018-071719. Vassiliev V. P., Lysenko V. A. New approach forthe study of thermodynamic properties of lanthanidecompounds. Electrochimica Acta. 2016;222: 1770–1775.DOI: https://doi.org/10.1016/j.electacta.2016.11.07520. Morachevsky A. G., Voronin G. F., Geyderich V. A.,Kutsenok I. B. Elektrokhimicheskie metody issledovaniyav t e r m o d i n a m i k e m e t a l l i c h e s k i k h s y s t e m .[Electrochemical methods of investigation inhermodynamics of metal systems]. Moscow:Akademkniga Publ.; 2003. 334 p. Available at: https://elibrary.ru/item.asp?id=19603291 (In Russ.)21. Babanly M. B., Yusibov Y. A. Elektrokhimicheskiemetody v termodinamike neorganicheskikh sistem[Electrochemical methods in thermodynamics ofinorganic systems]. Baku: BSU Publ.; 2011. 306 p.22. Imamaliyeva S. Z., Mehdiyeva I. F., Taghiyev D. B.et al. Thermodynamic investigations of the erbiumtellurides by EMF method. Physics and Chemistry ofSolid State. 2020;21(2): 312–318. DOI: https://doi.org/10.15330/pcss.21.2.312-31823. Hasanova G. S., Aghazade A. I., Yusibov Yu. A.,Babanly M. B. Thermodynamic investigation of theBi2Se3-Bi2Te3 system by the EMF method. Kondensirovannyesredy i mezhfaznye granitsy = CondensedMatter and Interphases. 2020;22(3): 310–319. DOI:https://doi.org/10.17308/kcmf.2020.22/296124. Imamaliyeva S. Z., Babanly D. M., Gasanly T. M.,et al.: Thermodynamic properties of Tl9GdTe6 andTlGdTe2. Russian Journal of Physical Chemistry A.2018;92(11): 2111–2116. DOI: https://doi.org/10.1134/s003602441811015825. Mansimova S. H., Orujlu E. N., Sultanova S. G.,Babanly M. B. Thermodynamic properties of Pb6Sb6Se17.Kondensirovannye sredy i mezhfaznye granitsy =Condensed Matter and Interphases. 2017;19(4): 536–541. https://doi.org/10.17308/kcmf.2017.19/23426. Imamaliyeva S. Z., Gasanly T. M., MahmudovaM. A. Thermodynamic properties of GdTe compound.Physics. 2017;22: 19–21. Available at: http://physics.gov.az/Dom/2017/AJP_Fizika_04_2017_en.pdf27. Imamaliyeva S. Z., Musayeva S. S., Babanly D. M.,Jafarov Y. I., Tagiyev D. B., Babanly M. B. Determinationof the thermodynamic functions of bismuthchalcoiodides by EMF method with morpholiniumformate as electrolyte. Thermochim. Acta. 2019; 679:178319–17825. DOI: https://doi.org/10.1016/j.tca.2019.17831928. Baza dannykh termicheskikh konstant veshchestv.Elektronnaya versiya pod. red. V. S. Yungmana. 2006[Database of thermal constants of substances.Electronic version V. S. Yungman (ed.). 2006]. 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引用次数: 0
摘要
本文介绍了用电动势和x射线衍射分析方法研究Tb-Te体系固相平衡和碲化铽热力学性质的结果。根据实验数据，确定了体系中形成了TbTe、Tb2Te3、TbTe2、TbTe3等化合物。为了研究TbTe3+Te、TbTe2+TbTe3和Tb2Te3+TbTe2两相区域的合金，测量了浓度池相对于TbTe电极的电动势。在TbTe+Tb2T3区域测量了浓度细胞相对于铽电极的电动势。结合300-450 K温度范围内两种类型的电动势测量，确定了合金中TbTe和Tb的部分热力学函数，并在此基础上计算了所指示碲化铽形成的标准热力学函数和标准熵。References1。稀土材料:性能与应用。美国。中华人民共和国出版社。2014。371 p.DOI: https://doi.org/10.1201/b170452。稀土元素:应用、出现、勘探、分析、回收和环境影响的综述。GeoscienceFrontiers。2019; 10(4): 1285 - 1290。DOI: https://doi.org/10.1016/j.gsf.2018.12.0053。Yarembash E. I.， Eliseev A. A. Khal 'kogenidyredkozemel 'nykh elementov[稀土元素硫属化合物]。莫斯科:Nauka Publ;1975. 258便士。(俄国人)4。Y-Sc。, La-Lu。格林无机化学手册。见:Hartmut Bergmann(编)，稀土元素，第8版，斯普林格出版社海德堡。柏林;1987.5. Muthuselvam I. P.， Nehru R.， Babu K. R.，Saranya K.， Kaul S. N.，陈世明，陈文涛，刘勇，郭国勇，修峰，Sankar R.。j .提供者。物质物理学报，2019;31(28):285802-5。DOI: https://doi.org/10.1088/1361 - 648 x/ab15706。黄慧，朱建军。稀土基纳米材料的电化学应用。2019; 144(23): 6789 - 6811。DOI: https://doi.org/10.1039/C9AN01562K7。Saint-Paul M.， Monceau P.。电荷密度波系统热力学性质的研究。放置电导率。物质物理。2019:1-5 DOI:https://doi.org/10.1155/2019/21382648。Cheikh D, Hogan B. E, Vo T, Allmen P. V, Lee K.，Smiadak D. M, Zevalkink A.， Dunn B. S.， Fleurial j . p。，丁少林。碲化镨:一种高温、高ZT热电材料。焦耳。2018;2(4): 698 - 709。DOI: https://doi.org/10.1016/j.joule.2018.01.0139。李大伟，金建辉，李大伟。碲化镧薄膜的化学合成及其超电容性能。胶体与界面科学学报，2017;490: 147 - 153。DOI: https://doi.org/10.1016/j.jcis.2016.11.02010。周学忠，张坤洪，肖军，朴建辉，Dickerson J- h。铕基二元纳米晶体EuX (X=O, S, Se, Te)的光学、磁性和磁光特性。纳米技术。2016;27(19):192001 - 5。DOI: https://doi.org/10.1088/0957-4484/27/19/19200111。Okamoto H.书桌手册二元合金相图。ASM国际。2000。900 p.12。Babanly M. B, Mashadiyeva L. F, Babanly D. M,Imamaliyeva S. Z, Tagiyev D. B, Yusibov Y. A。涉及电动势测量的三元硫系相平衡和热力学性质复杂研究的若干问题。无机化学学报，2019;64(13):1649-1672。DOI: https://doi.org/10.1134/s003602361913003513。Imamaliyeva S. Z.， Babanly D. M.， Tagiev D. B.，Babanly M. B.具有tl5te3结构的多组分硫族化物相发育的物理化学方面。复习一下。无机化学学报，2018;63(13):1703-1724 DOI: https://doi.org/10.1134/s003602361813004114。马萨斯基t.b.二元合金相图，第二版。ASM International, Materials Park.Ohio;1990. 3835页。DOI: https://doi.org/10.1002/adma.1991003121515。双金属系统图手册(3卷)。利亚基舍夫N.P.(编)莫斯科:Mashinostroenie出版社;1996、1997、2001年。(俄国人)16。叶利泽夫A. A.， Orlova I. G.， Martynova L. F.，Pechennikov A. V.， Chechernikov V.。无机材料。1987;23:1833-1835.17。Mills K. C.无机硫化物、硒化物和碲化物的热力学数据。伦敦:巴特沃斯;1974. 854 p.18。瓦西里耶夫V. P.，李senko V. A. Gaune-Escard m .热力学数据与周期律的关系。应用化学学报，2019;31(6):879-884。DOI: https://doi.org/10.1515/pac - 2018 - 071719。瓦西里耶夫V. P.，李森科V. A.。镧系化合物热力学性质研究的新方法。电化学学报，2016;22(2):1770-1775。DOI: https://doi.org/10.1016/j.electacta.2016.11.07520。Morachevsky A. G.， Voronin G. F.， Geyderich V. A.，Kutsenok i . B. elektrokhimichesky方法研究了一种新的研究方法，该方法研究了一种新的研究方法。
The paper presents the results of a study of solid-phase equilibria in the Tb–Te system and the thermodynamic properties of terbium tellurides obtained by the methods of electromotive forces and X-ray diffraction analysis. Based on the experimental data, it was established that the TbTe, Tb2Te3, TbTe2 и TbTe3 compounds are formed in the system. For the investigations of the alloys from the two-phase regions TbTe3+Te, TbTe2+TbTe3, and Tb2Te3+TbTe2, the EMF of concentration cells relative to the TbTe electrode was measured. The EMF of concentration cells relative to the terbium electrode was measured for the TbTe+Tb2T3 region. The partial thermodynamic functions of TbTe and Tb in alloys were determined bycombining the EMF measurements of both types in the 300–450 K temperature range, based on which the standard thermodynamic functions of formation and standard entropies of the indicated terbium tellurides were calculated.
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