稻壳中氮掺杂碳/ siox复合材料作为锂离子电池的高性能阳极

Jiajia Song, Shuowu Guo, Lingjiang Kou, Hui Liu, K. Kajiyoshi, Jiaxin Su, Peng Zheng
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引用次数: 0

摘要

为促进稻壳作为工业阳极材料的应用,以ZnCl2为形貌控制剂,通过简单的镁热还原法制备了氮掺杂碳/SiOx (N-C/SiOx)复合材料。该复合材料具有高可逆容量(100 mAg-1时1110 mAh g-1)、良好的循环稳定性和出色的倍率性能。由纳米颗粒组成的结构可以及时释放体积膨胀过程中产生的应力。此外,碳提供了良好的电子导电性,减少了副反应。稻壳驱动的N-C/SiOx复合材料具有优异的电化学性能,为硅基阳极材料的商业化提供了前景。
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Nitrogen-Doped Carbon/SiO x Composites from Rice Husks as a High-Performance Anode for Lithium-ion Batteries
To promote the application of rice husks for commercial anode materials, nitrogen-doped carbon/SiOx (N-C/SiOx) composites were prepared from rice husks using ZnCl2 as morphology control agent and via a simple magnesiothermic reduction method. The composites exhibit high reversible capacity (1110 mAh g-1 at 100 mAg-1), excellent cycling stability and outstanding rate performance. The structure consisted of nanoparticles can release the stress generated during volume expansion timely. In addition, carbon provides good electronic conductivity and reduce the side reaction. The rice husks-drived N-C/SiOx composites with excellent electrochemical performance, which provide a promise for commercial of Si-based anode materials.
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