X.D. Chai, W.S. Yang, R. Lu, Y.W. Cao, N. Lu, Y.S. Jiang, Y.B. Bai, T.J. Li
{"title":"一种新型两亲推拉二茂铁衍生物:Langmuir-Blodgett薄膜和二阶光学非线性","authors":"X.D. Chai, W.S. Yang, R. Lu, Y.W. Cao, N. Lu, Y.S. Jiang, Y.B. Bai, T.J. Li","doi":"10.1016/S0968-5677(98)00101-1","DOIUrl":null,"url":null,"abstract":"<div><p>The Langmuir–Blodgett (LB) films built from the mixture of an amphiphilic push–pull ferrocene derivative (<strong>P</strong>) and behenic acid were investigated. Langmuir films of <strong>P</strong> diluted by behenic acid exhibit a very good cohesion and the mixed films can easily be transferred onto solid substrates. Linear dichroism UV-visible and IR spectroscopy measurements of the mixed LB multilayers confirm that the molecules (<strong>P</strong>) are oriented to the substrate. The nonlinear optical experiments on the mixed monolayer deposited on the CaF<sub>2</sub> slide showed that <strong>P</strong> displayed efficient optical second harmonic generation (SHG) with a molecular hyperpolarizability (<em>β</em>) as high as 6.0×10<sup>-29</sup> e.s.u.</p></div>","PeriodicalId":22050,"journal":{"name":"Supramolecular Science","volume":"5 5","pages":"Pages 679-682"},"PeriodicalIF":0.0000,"publicationDate":"1998-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S0968-5677(98)00101-1","citationCount":"4","resultStr":"{\"title\":\"A novel amphiphilic push-pull ferrocene derivative: Langmuir–Blodgett films and second-order optical nonlinearity\",\"authors\":\"X.D. Chai, W.S. Yang, R. Lu, Y.W. Cao, N. Lu, Y.S. Jiang, Y.B. Bai, T.J. Li\",\"doi\":\"10.1016/S0968-5677(98)00101-1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The Langmuir–Blodgett (LB) films built from the mixture of an amphiphilic push–pull ferrocene derivative (<strong>P</strong>) and behenic acid were investigated. Langmuir films of <strong>P</strong> diluted by behenic acid exhibit a very good cohesion and the mixed films can easily be transferred onto solid substrates. Linear dichroism UV-visible and IR spectroscopy measurements of the mixed LB multilayers confirm that the molecules (<strong>P</strong>) are oriented to the substrate. The nonlinear optical experiments on the mixed monolayer deposited on the CaF<sub>2</sub> slide showed that <strong>P</strong> displayed efficient optical second harmonic generation (SHG) with a molecular hyperpolarizability (<em>β</em>) as high as 6.0×10<sup>-29</sup> e.s.u.</p></div>\",\"PeriodicalId\":22050,\"journal\":{\"name\":\"Supramolecular Science\",\"volume\":\"5 5\",\"pages\":\"Pages 679-682\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1998-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S0968-5677(98)00101-1\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Supramolecular Science\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0968567798001011\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Supramolecular Science","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0968567798001011","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
A novel amphiphilic push-pull ferrocene derivative: Langmuir–Blodgett films and second-order optical nonlinearity
The Langmuir–Blodgett (LB) films built from the mixture of an amphiphilic push–pull ferrocene derivative (P) and behenic acid were investigated. Langmuir films of P diluted by behenic acid exhibit a very good cohesion and the mixed films can easily be transferred onto solid substrates. Linear dichroism UV-visible and IR spectroscopy measurements of the mixed LB multilayers confirm that the molecules (P) are oriented to the substrate. The nonlinear optical experiments on the mixed monolayer deposited on the CaF2 slide showed that P displayed efficient optical second harmonic generation (SHG) with a molecular hyperpolarizability (β) as high as 6.0×10-29 e.s.u.
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