聚合物加工中的热控制和能量平衡

R. Deterre, P. Mousseau, A. Sarda, J. Launay
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引用次数: 0

摘要

橡胶工业在橡胶加工过程中面临着热控制不足的问题。在弹性体注射成型过程中,提高模具的能源效率是当前工业在能源消耗、生产率和产品质量方面面临的挑战。实验测量使我们能够了解工具的热,并显示模具表面和各种腔内的热非均质性。进行了橡胶的注射成型试验和模具能耗的热平衡试验。在橡胶工业中,资本货物消耗的能源中有20%来自加热过程;超过50%的热损失与模具的控制和隔热不足有关。模具的设计特别朝着减少加热质量和模具隔热的方向发展。图2:实验装置中使用的橡胶部件和流道。橡胶化合物是基于乙烯丙烯-二烯单体基体。该化合物的密度为1070 kg/ m3,导热系数为0.298 W/m /K,恒热质量为1490 J/kg/K。用橡胶过程分析仪(Rubber Process Analyzer, RPA)测量了胶料硫化的动力学曲线。2.3模具和热仪表模具配有热和压力传感器(参见图3)。图3:装有传感器的模具型腔视图。热装置能够测量橡胶在通道和各种空腔中的温度演变(Fekiri, et al., 2017)。用于数值固化模拟的模型几何如图4所示。图4:模型几何示意图。在边界Γ1和Γ5上施加模具温度调节。Ωm表示模具的金属边界,Ωis表示绝缘保护元件,Ωc表示橡胶部分。T+表示为优化的固化周期规定的模具温度。在图2中的阶段(1)中,橡胶部分的传热由式(1)、式(2)、式(3)描述,其中的源项与硫化反应的焓有关。c c c c c T Cp T T H T T(1)第II阶段的边界条件由式(8)和式(9)描述。T T T T T T T(2)
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Thermal control and energy balance in polymer processing
The rubber industry is facing a lack of thermal control during rubber processing. In the process of injection molding of elastomers, improving the energy efficiency of the tools is a current challenge for industry in terms of energy consumption, productivity and product quality. Experimental measurements allow us to understand the thermal of the tool and to show the thermal heterogeneities on the surface of the mold and in the various cavities. Tests of injection molding of the rubber and a thermal balance on the energy consumption of the tool are carried out. In the rubber industry, 20% of the energy consumed by capital goods comes from heating processes; more than 50% of heat losses are linked to insufficient control and thermal insulation of Molds. The design of the tooling evolves in particular towards the reduction of the heated mass and the thermal insulation of the molds. Figure 2: rubber parts and runners used in the experimental setup. The rubber compound is based on EthylenePropylene-Diene Monomer matrix. The compound has a density of 1070 kg /m3, a thermal conductivity of 0.298 W/m /K and a constant heat mass of 1490 J/kg/K. we used a RPA (Rubber Process Analyzer) in order to measure the kinetics curves of the rubber compound vulcanization. 2.3 Mold and thermal instrumentation The mold is equipped with thermal and pressure sensors (cf. Figure 3). Figure 3: view of the mold cavities equipped with sensors. The thermal device is able to measure the rubber temperature evolution in the channels and in the various cavities (Fekiri, et al., 2017). 3 THERMO-KINETIC MODEL OF MOLDING The model geometry used for the numerical curing simulation is represented in Figure 4. Figure 4: Schematic diagram of the model geometry. Mould temperature regulation is imposed on the boundaries Γ1 and Γ5. Ωm represents the metal boundaries of the mould, Ωis represents the insulating guarding element and Ωc represents the rubber part. T+ represents the mould temperature that is to be prescribed for the optimized curing cycle. During the phase (1) in Figure 2, heat transfer in the rubber part is described by equations (1),(2) and (3) with a source term related to the enthalpy of the vulcanization reaction.   c c c c c c T Cp T T H t t                   (1) The boundary conditions of phase II are described by equations (8) and (9).     T t t T t t       (2)
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Thermal control and energy balance in polymer processing A micromechanical model of filled elastomers based on reptation theory Experimental and numerical research of dynamic mechanical properties of magneto-sensitive elastomeric composites Thermal ageing of peroxide-cured NBR, Part II: Diffusion-limited oxidation and constitutive modelling Equibiaxial tension testing of rubber on a universal tension-testing machine
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