纳米BiVO4/InVO4/g-C3N4光催化剂高效降解酸性蓝92偶氮染料的制备

IF 2.1 4区 化学 Q3 CHEMISTRY, PHYSICAL Progress in Reaction Kinetics and Mechanism Pub Date : 2018-06-01 DOI:10.3184/146867818X15161889114493
M. Tasviri, Samin Bargozideh
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引用次数: 5

摘要

采用水热法和超声辅助水热法分别制备了BiVO4/InVO4和BiVO4/InVO4/g-C3N4。采用x射线衍射、扫描电镜和紫外-可见漫反射光谱对制备的样品进行了表征。制备的催化剂在可见光下对酸性蓝92 (AB92)进行了光催化活性测定。BiVO4/InVO4/g-C3N4对AB92的降解速率常数和效率均高于BiVO4/InVO4,表明BiVO4/InVO4/g-C3N4具有更好的光催化活性。这种增强可归因于BiVO4和InVO4粒子在g-C3N4表面的适当分散。此外,InVO4、BiVO4和g-C3N4的导带和价带边电位延长了电子-空穴对的寿命,有利于光催化效率的提高。
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Fabricating Nano-Sized BiVO4/InVO4/g-C3N4 Photocatalysts for Efficient Degradation of Acid Blue 92 Azo Dye
BiVO4/InVO4 and BiVO4/InVO4/g-C3N4 were prepared by hydrothermal and ultrasonic-assisted hydrothermal methods respectively. All prepared samples were characterised by X-ray diffraction, scanning electron microscopy and UV-Vis diffuse reflectance spectroscopy. The photocatalytic activity of the prepared catalysts was determined by degradation of Acid Blue 92 (AB92) under visible light. The rate constant and efficiency of AB92 degradation over BiVO4/InVO4/g-C3N4 was higher than that over BiVO4/InVO4 which indicates better photocatalytic activity of BiVO4/InVO4/g-C3N4. This enhancement can be attributed to the suitable dispersion of BiVO4 and InVO4 particles on the g-C3N4 surface. Furthermore, the conduction band and valence band edge potentials of InVO4, BiVO4 and g-C3N4 extend the life-time of electron–hole pairs which is beneficial for the improvement of photocatalytic efficiency.
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来源期刊
CiteScore
2.10
自引率
0.00%
发文量
5
审稿时长
2.3 months
期刊介绍: The journal covers the fields of kinetics and mechanisms of chemical processes in the gas phase and solution of both simple and complex systems.
期刊最新文献
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