甲烷+水=>甲醇+氢反应催化剂的研究

R. Larsson
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引用次数: 0

摘要

基于SET催化模型的概念和词汇,讨论了催化反应(如标题中的反应,即在非氧化环境下由甲烷产生甲醇)的催化剂应具有哪些特性。发现水(3652 cm-1)的n1振动与甲烷(1306 cm-1)的ny4振动共振相互作用。
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A proposal on a catalyst for the reaction methane + water => methanol + hydrogen
Based on the concepts and vocabulary of the SET model of catalysis a discussion is performed on what properties should characterize a catalyst promoting a reaction such as the one in the title, i.e., the production of methanol from methane in a non-oxidative environment. It is found that the n1 vibration of water (3652 cm-1 ) and the ny4 vibration of methane (1306 cm-1) interact in resonance.
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