非线性阻力作用下分子气体的Mpemba效应

Andrés Santos, A. Prados
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引用次数: 31

摘要

我们研究了Mpemba效应——在具有非线性粘性阻力的分子气体中,最初较热的样品冷却得更快。具体来说,气体粒子之间通过弹性碰撞和平衡状态下的背景流体相互作用。因此,在动态论的框架内,我们的气体可以用恩斯科格—福克—普朗克方程来描述。分析是在第一个Sonine近似中进行的,其中温度的演变与过量峰度的演变是耦合的。这种耦合导致Mpemba效应的出现,这种效应在弛豫的早期阶段和两个样品的初始温度足够接近时被观察到。这允许一个简单的理论的发展,线性化温度演变的参考温度-即初始温度更接近渐近平衡值。线性理论提供了这种效应的半定量描述,包括交叉时间和最大温差的表达式。我们还讨论了线性化理论的局限性。
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Mpemba effect in molecular gases under nonlinear drag
We look into the Mpemba effect---the initially hotter sample cools sooner---in a molecular gas with nonlinear viscous drag. Specifically, the gas particles interact among them via elastic collisions and also with a background fluid at equilibrium. Thus, within the framework of kinetic theory, our gas is described by an Enskog--Fokker--Planck equation. The analysis is carried out in the first Sonine approximation, in which the evolution of the temperature is coupled to that of the excess kurtosis. This coupling leads to the emergence of the Mpemba effect, which is observed in an early stage of the relaxation and when the initial temperatures of the two samples are close enough. This allows for the development of a simple theory, linearizing the temperature evolution around a reference temperature---namely the initial temperature closer to the asymptotic equilibrium value. The linear theory provides a semiquantitative description of the effect, including expressions for the crossover time and the maximum temperature difference. We also discuss the limitations of our linearized theory.
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