一种可折叠的高透明氟化聚酰亚胺(HFBAPP/6FDA)薄膜材料,用于透明柔性基板

IF 1 4区 化学 Q4 POLYMER SCIENCE Polimeros-ciencia E Tecnologia Pub Date : 2021-05-31 DOI:10.1590/0104-1428.10520
Chuanhao Cao, Lizhu Liu, Xiaorui Zhang
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引用次数: 3

摘要

摘要柔性透明基板材料,与传统基板材料相比,能够承受较高的动态应变。提供了一种具有透明、尺寸稳定、耐腐蚀、耐电等优点的柔性透明材料。通过引入高F原子含量的结构和精细的优化工艺,制备了聚酰亚胺(PI)薄膜,提高了薄膜的各项性能。通过梯度真空和二次溶解对膜的性能进行了优化,使膜在400 nm处的透过率达到82%。具有低介电常数和低介电损耗的薄膜的击穿强度为202 kV/mm。薄膜的玻璃化转变温度为267℃,热膨胀系数为35ppm/k(30℃~270℃),具有良好的热尺寸稳定性。因此,这种聚酰亚胺薄膜在折叠手机上是一种具有极高应用潜力的光电器件,而PI薄膜是最好的屏幕材料。
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A foldable high transparent fluorinated polyimide (HFBAPP/6FDA) film material for transparent flexible substrate
Abstract Flexible transparent substrate materials, which was able to withstand high dynamic strain, in contrast to traditional substrate materials. A flexible and transparent material with advantages including transparency, stable size, and excellent corrosion and electrical resistance was provided. The polyimide(PI) film was prepared by introducing a structure with a high content of F atom and a fine optimization process to enhance the various properties of the film. However, the properties of the films were optimized effectively by gradient vacuum and secondary dissolution so that the film had a transmittance at 400 nm of 82%. The films with low dielectric constant and low dielectric loss represent the breakdown strength of 202 kV/mm. The glass transition temperature of the film was 267 °C, and the thermal expansion coefficient was 35ppm/k (30 °C~270 °C), indicated outstanding thermal dimensional stability. Therefore, this polyimide film was an optoelectronic device with extremely high application potential on the folding mobile phone and the PI film is the finest materials of screen.
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来源期刊
Polimeros-ciencia E Tecnologia
Polimeros-ciencia E Tecnologia 化学-高分子科学
CiteScore
2.00
自引率
0.00%
发文量
14
审稿时长
6 months
期刊介绍: Polímeros is a quarterly publication of the Associação Brasileira de Polímeros - ABPol (Brazilian Polymer Association), which publishes Review Articles, Original Articles and Short Communications, disclosing advances in the knowledge of Polymer Science and Technology.
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