功能表面包覆磁赤铁矿纳米颗粒的结构和磁性表征

P. Demchenko, N. Mitina, A. Zaichenko, N. Nedelko, S. Lewińska, A. Ślawska-Waniewska, P. Dłużewski, M. Bilska, S. Ubizskii
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引用次数: 1

摘要

在功能性低过氧化物表面活性剂的作用下,通过模板法合成了磁性γ-Fe2O3核和有机壳组成的纳米粒子,并在其表面引发接枝聚合。采用x射线衍射(XRD)、透射电镜(TEM)和磁性测量(PPMS)对制备的核-壳纳米粒子的磁性体系进行了表征。XRD结果证实了γ-Fe2O3相的存在,纳米颗粒的平均直径约为10 nm。所得粒子在室温下具有超顺磁性。磁测量也表明在低温下粒子间有足够强的偶极相互作用。
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Structural and magnetic characterization of functional surface coated maghemite nanoparticles
Nanoparticles composed of magnetic γ-Fe2O3 core and organic shell were synthesized via template synthesis in the presence of functional oligoperoxide surfactants and further graft-polymerization initiated from their surface. X-ray diffraction (XRD), transmission electron microscopy (TEM) and magnetic measurements (PPMS) were used to characterize the obtained magnetic system of core-shell nanoparticles. XRD results confirm the existence of γ-Fe2O3 phase as well as show an average diameter of nanoparticles around 10 nm. The obtained particles are superparamagnetic at the room temperature. Magnetic measurements indicate also sufficiently strong dipolar interparticle interactions at low temperatures.
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