喀麦隆棕榈仁籽油生物润滑剂的合成与表征

M. Alang, M. Ndikontar, Y. Sani, P. Ndifon
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引用次数: 20

摘要

以喀麦隆棕榈仁油(PKO)为原料,采用双酯交换法合成生物润滑剂,第一阶段生成甲酯,然后与三甲基丙烷(TMP)进行酯交换,得到PKO生物润滑剂,催化剂来源于车前草皮(城市垃圾)。两种催化剂的产率非常相似(本地生产的为48%,传统的为51%),这表明本地生产的催化剂可以实现增值。对合成的生物润滑剂进行了理化性质的表征。比重为1.2,ASTM颜色为1.5,浊点为0°C,倾点为-9°C, 40°C时粘度为509.80 cSt, 100°C时粘度为30.80 cSt,粘度指数为120,闪点大于210°C,燃点大于220°C。这种合成的生物润滑剂被发现可与工业上从矿物来源生产的商业T-46石油润滑剂样品相媲美。因此,我们使用当地材料生产生物润滑剂,使用从城市垃圾中提取的廉价碱性催化剂。
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Synthesis and Characterisation of a Biolubricant from Cameroon Palm Kernel Seed Oil Using a Locally Produced Base Catalyst from Plantain Peelings
Biolubricant was synthesized from Cameroon palm kernel oil (PKO) by double transesterification, producing methyl esters in the first stage which were then transesterified with trimethylolpropane (TMP) to give the PKO biolubricant in the presence of a base catalyst obtained from plantain peelings (municipal waste). The yields from both catalysts were significantly similar (48% for the locally produced and 51% for the conventional) showing that the locally produced catalyst could be valorized. The synthesized biolubricant was characterized by measuring its physical and chemical properties. The specific gravity of 1.2, ASTM color of 1.5, cloud point of 0°C, pour point of -9°C, viscosities at 40°C of 509.80 cSt and at 100°C of 30.80 cSt, viscosity index of 120, flash point greater than 210°C and a fire point greater than 220°C were obtained. This synthesized biolubricant was found to be comparable to commercial T-46 petroleum lubricant sample produced industrially from mineral sources. We have therefore used local materials to produce a biolubricant using a cheap base catalyst produced from municipal waste.
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