{"title":"光催化还原配位二氮制氨-单核与双核乙二胺四乙酸钌配合物","authors":"N.Nageswara Rao","doi":"10.1016/0304-5102(94)00097-2","DOIUrl":null,"url":null,"abstract":"<div><p>Experiments were conducted aiming for the reduction of coordinated nitrogen in mononuclear end-on dinitrogen complex, [Ru (Hedta) N<sub>2</sub>]<sup>−</sup> and dinuclear bridged complex, [Ru (Hedta)]<sub>2</sub>N<sup>2−</sup><sub>2</sub> using the conduction band electrons of illuminated Pt/CdS (λ<sub>ex</sub>= 505 nm). It has been found that the dinitrogen in mononuclear end-on complex is more easily reduced to ammonia.</p></div>","PeriodicalId":16567,"journal":{"name":"分子催化","volume":"93 1","pages":"Pages 23-27"},"PeriodicalIF":0.0000,"publicationDate":"1994-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0304-5102(94)00097-2","citationCount":"5","resultStr":"{\"title\":\"Photocatalytic reduction of coordinated dinitrogen to ammonia — mononuclear versus dinuclear ethylenediaminetetraacetato ruthenium complexes\",\"authors\":\"N.Nageswara Rao\",\"doi\":\"10.1016/0304-5102(94)00097-2\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Experiments were conducted aiming for the reduction of coordinated nitrogen in mononuclear end-on dinitrogen complex, [Ru (Hedta) N<sub>2</sub>]<sup>−</sup> and dinuclear bridged complex, [Ru (Hedta)]<sub>2</sub>N<sup>2−</sup><sub>2</sub> using the conduction band electrons of illuminated Pt/CdS (λ<sub>ex</sub>= 505 nm). It has been found that the dinitrogen in mononuclear end-on complex is more easily reduced to ammonia.</p></div>\",\"PeriodicalId\":16567,\"journal\":{\"name\":\"分子催化\",\"volume\":\"93 1\",\"pages\":\"Pages 23-27\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1994-09-27\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0304-5102(94)00097-2\",\"citationCount\":\"5\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"分子催化\",\"FirstCategoryId\":\"1089\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0304510294000972\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q4\",\"JCRName\":\"Chemical Engineering\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"分子催化","FirstCategoryId":"1089","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0304510294000972","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"Chemical Engineering","Score":null,"Total":0}
Photocatalytic reduction of coordinated dinitrogen to ammonia — mononuclear versus dinuclear ethylenediaminetetraacetato ruthenium complexes
Experiments were conducted aiming for the reduction of coordinated nitrogen in mononuclear end-on dinitrogen complex, [Ru (Hedta) N2]− and dinuclear bridged complex, [Ru (Hedta)]2N2−2 using the conduction band electrons of illuminated Pt/CdS (λex= 505 nm). It has been found that the dinitrogen in mononuclear end-on complex is more easily reduced to ammonia.
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