表面活性剂(UMP)用于原油包水乳状液(W/O)的乳化和稳定

N. H. Abdurahman, H. A. Magdib
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引用次数: 0

摘要

研究了UMP NS-19-02表面活性剂稳定油包水(W/O)乳状液的配方及性能评价,并探讨了该乳状液在马来西亚原油胶状液稳定中的应用。利用马来西亚炼油厂的两种石油,即Tapis石油和Tapis- Mesilla混合油,制成油包水乳液。对影响乳化液特性和稳定性的各种因素进行了评价。研究发现,随着表面活性剂含量的增加,经UMP NS-19-02改性的油包水乳状液的稳定性提高,导致原油-水界面张力(IFT)下降。而W/O乳液的最佳配方是W/O比为50:50,表面活性剂为1.0%。此外,提高乳状液的含油量、盐浓度、搅拌时间、搅拌速度和pH值可以提高乳状液的稳定性。它还提高了初始混合的温度,这大大降低了配方乳剂的粘度。结果表明,使用UMP NS-19-02表面活性剂可以形成稳定的乳剂。
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Surfactant (UMP) for emulsification and stabilization of water-in-crude oil emulsions (W/O)
The purpose of this research is to look into the formulation and evaluation of concentrated water-in-oil (W/O) emulsions stabilized by UMP NS-19-02 surfactant and their application for crude oil emulsion stabilization using gummy Malaysian crude oil. A two-petroleum oil from Malaysia oil refinery, i.e., Tapis petroleum oil and Tapis- Mesilla blend, were utilized to make water-in-oil emulsions. The various factors influencing emulsion characteristics and stability were evaluated. It was discovered that the stability of the water-in-oil emulsion improved by UMP NS-19-02 improved as the surfactant content rises, resulting in the decline of the crude oil-water interfacial tension (IFT). Nevertheless, the most optimum formulation of W/O emulsion was a 50:50 W/O ratio with 1.0% surfactant. Additionally, raising the oil content, salt concentration, duration and mixing speed, and pH of the emulsion resulted in higher emulsion stability. It also raised the temperature of the initial mixing, which significantly decreased the formulated emulsions' viscosity. The results showed that stable emulsions could be formed using the UMP NS-19-02 surfactant.
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