{"title":"锌/铁体系在碳酸氢钠和硝酸钠溶液中的细胞逆转","authors":"J. Chamberlain","doi":"10.1016/0376-4583(85)90139-6","DOIUrl":null,"url":null,"abstract":"<div><p>Reversal in the zinc/iron galvanic cell occurs in aerated solutions of both sodium bicarbonate and sodium nitrate.</p><p>The sodium nitrate reversal occurs over the temperature range from 25 °C to 80 °C. The time to reversal and the stability of the reversed cell are concentration and temperature dependent. The most rapid and stable reversal at 80 °C occurs in 0.1 mM solution. At room temperature the role of the electrodes cycles, but the long-term tendency is for the zinc to become the cathode in the system.</p></div>","PeriodicalId":22037,"journal":{"name":"Surface Technology","volume":"25 3","pages":"Pages 229-257"},"PeriodicalIF":0.0000,"publicationDate":"1985-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0376-4583(85)90139-6","citationCount":"4","resultStr":"{\"title\":\"Cell reversal of the zinc/iron system in sodium bicarbonate and sodium nitrate solutions\",\"authors\":\"J. Chamberlain\",\"doi\":\"10.1016/0376-4583(85)90139-6\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Reversal in the zinc/iron galvanic cell occurs in aerated solutions of both sodium bicarbonate and sodium nitrate.</p><p>The sodium nitrate reversal occurs over the temperature range from 25 °C to 80 °C. The time to reversal and the stability of the reversed cell are concentration and temperature dependent. The most rapid and stable reversal at 80 °C occurs in 0.1 mM solution. At room temperature the role of the electrodes cycles, but the long-term tendency is for the zinc to become the cathode in the system.</p></div>\",\"PeriodicalId\":22037,\"journal\":{\"name\":\"Surface Technology\",\"volume\":\"25 3\",\"pages\":\"Pages 229-257\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1985-07-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0376-4583(85)90139-6\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Surface Technology\",\"FirstCategoryId\":\"1087\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0376458385901396\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Surface Technology","FirstCategoryId":"1087","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0376458385901396","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Cell reversal of the zinc/iron system in sodium bicarbonate and sodium nitrate solutions
Reversal in the zinc/iron galvanic cell occurs in aerated solutions of both sodium bicarbonate and sodium nitrate.
The sodium nitrate reversal occurs over the temperature range from 25 °C to 80 °C. The time to reversal and the stability of the reversed cell are concentration and temperature dependent. The most rapid and stable reversal at 80 °C occurs in 0.1 mM solution. At room temperature the role of the electrodes cycles, but the long-term tendency is for the zinc to become the cathode in the system.
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