{"title":"锡和钛醇氧化物与3-戊烯酸反应的光谱研究","authors":"Gamze Bulut, Asgar Kayan","doi":"10.2174/1874343900802010038","DOIUrl":null,"url":null,"abstract":"Tin and titanium pentenoate have been prepared from tin(IV) butoxide and titanium (IV) isopropoxide in alcohol and 3-pentenoic acid. Reactions of Sn(OBu n )4 and Ti(OPr i )4 with 3-pentenoic acid in 1:1 molar ratio were studied in butanol and propanol solution at room temperature by sol-gel process. The complexations were investigated by 13 C, 1 H- NMR and FT-IR spectroscopy. 13 C{ 1 H}, 1 H-NMR and FT-IR spectra showed that 3-pentenoic acid completely reacted with Sn(OBu n )4 and Ti(OPr i )4. These new products were hydrolyzed by water in ratio of 1:4 (M(OR)4 /H2O, M: Sn, Ti, R: butyl and isopropyl). The stability of hydrolyzed products was investigated by 13 C, 1 H NMR and FT-IR. After hydrolysis, it was seen that no 3-pentenoic acid was released from (Ti(OPr i )3(PA))n and but was released from (Sn(OBu n )3(PA))n un- der the studied conditions.","PeriodicalId":22718,"journal":{"name":"The Open Macromolecules Journal","volume":"2015 1","pages":"38-42"},"PeriodicalIF":0.0000,"publicationDate":"2008-11-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":"{\"title\":\"Spectroscopic Investigation on the Reactions of Tin and Titanium Alkoxides with 3-Pentenoic Acid\",\"authors\":\"Gamze Bulut, Asgar Kayan\",\"doi\":\"10.2174/1874343900802010038\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Tin and titanium pentenoate have been prepared from tin(IV) butoxide and titanium (IV) isopropoxide in alcohol and 3-pentenoic acid. Reactions of Sn(OBu n )4 and Ti(OPr i )4 with 3-pentenoic acid in 1:1 molar ratio were studied in butanol and propanol solution at room temperature by sol-gel process. The complexations were investigated by 13 C, 1 H- NMR and FT-IR spectroscopy. 13 C{ 1 H}, 1 H-NMR and FT-IR spectra showed that 3-pentenoic acid completely reacted with Sn(OBu n )4 and Ti(OPr i )4. These new products were hydrolyzed by water in ratio of 1:4 (M(OR)4 /H2O, M: Sn, Ti, R: butyl and isopropyl). The stability of hydrolyzed products was investigated by 13 C, 1 H NMR and FT-IR. After hydrolysis, it was seen that no 3-pentenoic acid was released from (Ti(OPr i )3(PA))n and but was released from (Sn(OBu n )3(PA))n un- der the studied conditions.\",\"PeriodicalId\":22718,\"journal\":{\"name\":\"The Open Macromolecules Journal\",\"volume\":\"2015 1\",\"pages\":\"38-42\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2008-11-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"The Open Macromolecules Journal\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2174/1874343900802010038\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"The Open Macromolecules Journal","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2174/1874343900802010038","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Spectroscopic Investigation on the Reactions of Tin and Titanium Alkoxides with 3-Pentenoic Acid
Tin and titanium pentenoate have been prepared from tin(IV) butoxide and titanium (IV) isopropoxide in alcohol and 3-pentenoic acid. Reactions of Sn(OBu n )4 and Ti(OPr i )4 with 3-pentenoic acid in 1:1 molar ratio were studied in butanol and propanol solution at room temperature by sol-gel process. The complexations were investigated by 13 C, 1 H- NMR and FT-IR spectroscopy. 13 C{ 1 H}, 1 H-NMR and FT-IR spectra showed that 3-pentenoic acid completely reacted with Sn(OBu n )4 and Ti(OPr i )4. These new products were hydrolyzed by water in ratio of 1:4 (M(OR)4 /H2O, M: Sn, Ti, R: butyl and isopropyl). The stability of hydrolyzed products was investigated by 13 C, 1 H NMR and FT-IR. After hydrolysis, it was seen that no 3-pentenoic acid was released from (Ti(OPr i )3(PA))n and but was released from (Sn(OBu n )3(PA))n un- der the studied conditions.
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