熔体流动改性剂对二次聚丙烯-硅酸铝微球聚合物复合材料物理力学性能的影响

A. Psyanchin, E. Zakharova, V. Zakharov
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引用次数: 0

摘要

热塑性塑料在回收过程中的特点是机械和热氧化降解,这导致塑料成品的使用性能恶化。在加工过程中使二级原料具有最佳特性的一种可能选择是加入硅酸铝微球和增加熔体流动性的改性剂。本文介绍了硬脂酸存在下硅酸铝微球填充二次聚丙烯聚合物复合材料的流变性能和物理力学性能的研究结果。结果表明,硬脂酸增加了熔体的流动性,改善了机械加工过程中的工艺性能,包括促进硅酸铝微球颗粒在聚合物体积中的均匀分布。硬脂酸的最佳浓度为重量的0.5%,在此浓度下,熔体流动速率的最大增加,抗拉强度的下降不超过16%,以及对动态冲击的抵抗能力的增加,而表征材料刚度的弹性模量没有显著变化。
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Effect of melt flow modifier on the physico-mechanical properties of a polymer composite based on secondary polypropylene and aluminosilicate microspheres
Thermoplastics in the recycling process are characterized by mechanical and thermo-oxidative degradation, which leads to deterioration of the operational properties of finished plastic products. A possible option for giving the secondary raw material optimal characteristics during processing may be the inclusion of aluminosilicate microspheres and modifiers that increase the fluidity of the melt. This paper presents the results of the study of rheological and physico-mechanical properties of polymer composites based on secondary polypropylene filled with aluminosilicate microspheres in the presence of stearic acid. It is shown that stearic acid increases the fluidity of the melt, improves technological performance during mechanical processing, including promotes uniform distribution of particles of aluminosilicate microspheres in the polymer volume. The optimal concentration of stearic acid is 0.5 % by weight, at which there is a maximum increase in the melt flow rate, a decrease in tensile strength of no more than 16 %, as well as an increase in resistance to dynamic impact without a significant change in the elastic modulus characterizing the stiffness of the material.
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