Cocrfeni和Cocrfemnni高熵合金中扩散热力学因素的实验评定

I. Belova, G. Murch
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引用次数: 0

摘要

在这篇文章中,作为对Scripta Materialia, v.157, p.81, 2018的论文的回应,我们表明,用于分析多组分合金中相互扩散的伪二元方法具有曼宁因子(空缺风因子)的参考价值,这与真正的二元相互扩散有很大不同。在真正的二元互扩散中,这个因素通常与统一进行比较。在伪二元分析中,必须将该参考值改为N1+N2的倒数,其中Ni为组分(摩尔分数),组分1和组分2为相应实验中具有不同末端组分的原子组分。
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Comments on Experimental Assessment of the Thermodynamic Factor for Diffusion in Cocrfeni and Cocrfemnni High Entropy Alloys
In this contribution, as a response to the paper in Scripta Materialia, v.157, p.81, 2018, we show that the pseudo-binary approach for analysis of interdiffusion in multicomponent alloys has its reference value of the Manning factor (vacancy-wind factor) that is very different from true binary interdiffusion. In true binary interdiffusion, this factor is usually compared with unity. In the pseudo-binary analysis this reference value must be changed to the inverse of N1+N2, where Ni are the compositions (mole fractions), and components 1 and 2 are the atomic components that have different terminal compositions in the corresponding experiment.
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