{"title":"Cocrfeni和Cocrfemnni高熵合金中扩散热力学因素的实验评定","authors":"I. Belova, G. Murch","doi":"10.2139/ssrn.3406391","DOIUrl":null,"url":null,"abstract":"In this contribution, as a response to the paper in Scripta Materialia, v.157, p.81, 2018, we show that the pseudo-binary approach for analysis of interdiffusion in multicomponent alloys has its reference value of the Manning factor (vacancy-wind factor) that is very different from true binary interdiffusion. In true binary interdiffusion, this factor is usually compared with unity. In the pseudo-binary analysis this reference value must be changed to the inverse of N<sub>1</sub>+N<sub>2</sub>, where N<sub>i</sub> are the compositions (mole fractions), and components 1 and 2 are the atomic components that have different terminal compositions in the corresponding experiment.","PeriodicalId":18731,"journal":{"name":"Materials Processing & Manufacturing eJournal","volume":"120 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2019-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Comments on Experimental Assessment of the Thermodynamic Factor for Diffusion in Cocrfeni and Cocrfemnni High Entropy Alloys\",\"authors\":\"I. Belova, G. Murch\",\"doi\":\"10.2139/ssrn.3406391\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"In this contribution, as a response to the paper in Scripta Materialia, v.157, p.81, 2018, we show that the pseudo-binary approach for analysis of interdiffusion in multicomponent alloys has its reference value of the Manning factor (vacancy-wind factor) that is very different from true binary interdiffusion. In true binary interdiffusion, this factor is usually compared with unity. In the pseudo-binary analysis this reference value must be changed to the inverse of N<sub>1</sub>+N<sub>2</sub>, where N<sub>i</sub> are the compositions (mole fractions), and components 1 and 2 are the atomic components that have different terminal compositions in the corresponding experiment.\",\"PeriodicalId\":18731,\"journal\":{\"name\":\"Materials Processing & Manufacturing eJournal\",\"volume\":\"120 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2019-06-19\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Materials Processing & Manufacturing eJournal\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.2139/ssrn.3406391\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Materials Processing & Manufacturing eJournal","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2139/ssrn.3406391","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Comments on Experimental Assessment of the Thermodynamic Factor for Diffusion in Cocrfeni and Cocrfemnni High Entropy Alloys
In this contribution, as a response to the paper in Scripta Materialia, v.157, p.81, 2018, we show that the pseudo-binary approach for analysis of interdiffusion in multicomponent alloys has its reference value of the Manning factor (vacancy-wind factor) that is very different from true binary interdiffusion. In true binary interdiffusion, this factor is usually compared with unity. In the pseudo-binary analysis this reference value must be changed to the inverse of N1+N2, where Ni are the compositions (mole fractions), and components 1 and 2 are the atomic components that have different terminal compositions in the corresponding experiment.