利用多孔阳极氧化氧化铝膜制备一维多组分纳米结构

Loh Pui Yee, Liu Chenmin, Pua Weicheng, K. Yu, Chin Wee Shong
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引用次数: 0

摘要

在这篇简短的综述中,我们报道了利用阳极氧化氧化铝膜(AAM)制备各种有趣的多组分纳米结构,包括核壳纳米线阵列、多壁纳米管、分段纳米线和多层堆叠纳米盘。我们证明了金属(Cu, Ni和Au)和聚合物(PPV和PPy)一维(1D)阵列可以很容易地通过电化学沉积到AAM中。通过优化实验设计和条件,我们开发了各种多组分纳米结构的技术,如聚合物/金属或金属/金属核-壳纳米线以及纳米管,并对纳米结构的长度和壳厚度进行了较好的控制。此外,我们将此方法扩展到制作分段纳米线和多层堆叠纳米盘。在组装过程中,选择性功能化导致纳米线的端上或侧上粘附。我们说明了在这个长度尺度上利用这些一维阵列来呈现具有发光和/或磁性的图案的可能性。
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FACILE FABRICATION OF ONE-DIMENSIONAL MULTI-COMPONENT NANOSTRUCTURES USING POROUS ANODIZED ALUMINA MEMBRANE
In this short review, we report the facile fabrication of various interesting multi-component nanostructures including arrays of core-shell nanowires, multiwall nanotubes, segmented nanowires and multilayer stacked nanodisks, using anodized alumina membrane (AAM). We demonstrate that metallic (Cu, Ni and Au) and polymeric (PPV and PPy) one-dimensional (1D) arrays can be readily prepared by electrochemical deposition into the AAM. By optimizing the experimental design and conditions, we developed techniques to produce various multi-component nanostructures such as polymer/metal or metal/metal core-shell nanowires as well as nanotubes, with reasonably good control over both the length and the shell thickness of the nanostructures. Furthermore, we extend this method to make segmented nanowires as well as multilayer stacked nanodisks. Selective functionalization of the segmented nanowires resulted in end-on or side-on adhesion of nanowires during assembly. We illustrate the possibility of utilizing these 1D arrays to present patterns with luminescent and/or magnetic properties at this length scale.
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