{"title":"含有e -双键和外亚甲基的1,3-二烯的构造","authors":"J. Eshelby, P. Parsons, N. C. Sillars, P. Crowley","doi":"10.1039/C39950001497","DOIUrl":null,"url":null,"abstract":"The use of a tandem Ireland Claisen rearrangement followed by an in situ silicon mediated epoxide fragmentation provides an efficient entry into 1,3-dienes containing an E-double bond and an exo-methylene group; initial results regarding remote chirality control are reported.","PeriodicalId":17282,"journal":{"name":"Journal of The Chemical Society, Chemical Communications","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1995-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"7","resultStr":"{\"title\":\"The construction of 1,3-dienes containing an E-double bond and an exo-methylene group\",\"authors\":\"J. Eshelby, P. Parsons, N. C. Sillars, P. Crowley\",\"doi\":\"10.1039/C39950001497\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The use of a tandem Ireland Claisen rearrangement followed by an in situ silicon mediated epoxide fragmentation provides an efficient entry into 1,3-dienes containing an E-double bond and an exo-methylene group; initial results regarding remote chirality control are reported.\",\"PeriodicalId\":17282,\"journal\":{\"name\":\"Journal of The Chemical Society, Chemical Communications\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1995-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"7\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society, Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C39950001497\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society, Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C39950001497","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
The construction of 1,3-dienes containing an E-double bond and an exo-methylene group
The use of a tandem Ireland Claisen rearrangement followed by an in situ silicon mediated epoxide fragmentation provides an efficient entry into 1,3-dienes containing an E-double bond and an exo-methylene group; initial results regarding remote chirality control are reported.
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