{"title":"无机盐与水的液体混合物中溶液化学的某些方面","authors":"J Braunstein","doi":"10.1016/0073-8085(68)80012-9","DOIUrl":null,"url":null,"abstract":"<div><p>Experimental and theoretical investigations of some thermodynamic, transport and structural properties of very concentrated aqueous electrolyte solutions are reviewed. Attention is focussed on the range of concentrations between anhydrous molten salts and the hydrate melts. In this region, the hydration shells of the ions are incomplete, and ion-ion, ion-water, and water-water interactions must be considered. Extensions of the Debye-Huckel theory are not valid in this region, and models based on anhydrous molten salts may be useful.</p></div>","PeriodicalId":100676,"journal":{"name":"Inorganica Chimica Acta Reviews","volume":"2 ","pages":"Pages 19-30"},"PeriodicalIF":0.0000,"publicationDate":"1968-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0073-8085(68)80012-9","citationCount":"32","resultStr":"{\"title\":\"Some aspects of solution chemistry in liquid mixtures of inorganic salts with water\",\"authors\":\"J Braunstein\",\"doi\":\"10.1016/0073-8085(68)80012-9\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Experimental and theoretical investigations of some thermodynamic, transport and structural properties of very concentrated aqueous electrolyte solutions are reviewed. Attention is focussed on the range of concentrations between anhydrous molten salts and the hydrate melts. In this region, the hydration shells of the ions are incomplete, and ion-ion, ion-water, and water-water interactions must be considered. Extensions of the Debye-Huckel theory are not valid in this region, and models based on anhydrous molten salts may be useful.</p></div>\",\"PeriodicalId\":100676,\"journal\":{\"name\":\"Inorganica Chimica Acta Reviews\",\"volume\":\"2 \",\"pages\":\"Pages 19-30\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1968-12-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0073-8085(68)80012-9\",\"citationCount\":\"32\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Inorganica Chimica Acta Reviews\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0073808568800129\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Inorganica Chimica Acta Reviews","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0073808568800129","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Some aspects of solution chemistry in liquid mixtures of inorganic salts with water
Experimental and theoretical investigations of some thermodynamic, transport and structural properties of very concentrated aqueous electrolyte solutions are reviewed. Attention is focussed on the range of concentrations between anhydrous molten salts and the hydrate melts. In this region, the hydration shells of the ions are incomplete, and ion-ion, ion-water, and water-water interactions must be considered. Extensions of the Debye-Huckel theory are not valid in this region, and models based on anhydrous molten salts may be useful.