紫外光对低密度和高密度聚乙烯降解失重和红外光谱的影响

Prakash Bhuyar, Nurul Aqilah Binti Mohd Tamizi, Mohd Hasbi Ab. Rahim, Gaanty Pragas Maniam, Natanamurugaraj Govindan
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引用次数: 2

摘要

本研究旨在了解聚乙烯聚合物降解过程中广泛存在的相关知识。聚乙烯降解过程中涉及的处理方式为物理处理,降解方法为紫外光光降解。通过使用紫外线照射光的物理处理,它可以通过影响将聚合物结合在一起的键来破坏和削弱塑料。从FTIR和SEM分析得到的结果来看,经过30天的紫外处理,LDPE的FTIR光谱比HDPE的FTIR光谱显示出更高的透过率。这说明高透射率的LDPE样品中吸收光的键数较少,而低透射率的HDPE样品中吸收光的键数较多,其振动能量与入射光相对应。SEM结果显示,用于LDPE塑料片材的聚乙烯表现出最好的降解效果,与HDPE塑料片材的21.6%相比,聚乙烯片材的重量损失减少了87.5%。
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Effect of ultraviolet light on the degradation of Low-Density and High-Density Polyethylene characterized by the weight loss and FTIR
In this study, the research was made to understand the knowledge widely related to the degradation process of polyethylene polymer. The mode of treatment that involves in the degradation process of polyethylene is physical treatment while the method of degradation used is photo-degradation of UV light. By using the physical treatment of UV irradiation light, it helps by affecting the bonding that holds the polymer together to break and weakens the plastic. From the result obtained in FTIR and SEM analysis, in FTIR spectrum of LDPE shows higher transmittance compared to FTIR spectrum of HDPE both UV-treated for 30 days. This indicates the high transmittance have few bonds to absorb light in the LDPE sample, low transmittance in HDPE sample means has high population of bonds which have vibrational energies corresponding to the incident light. For SEM result, the polyethylene for LDPE plastic sheet shows the best results for degradation and managed to reduce the weight loss at 87.5% compared to HDPE plastic which at 21.6%.
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