D.A. Oleskevich, N. Ghahramany , W.P. Weglarz, H. Peemoeller
{"title":"二维时域核磁共振研究木材界面自旋-自旋耦合","authors":"D.A. Oleskevich, N. Ghahramany , W.P. Weglarz, H. Peemoeller","doi":"10.1006/jmrb.1996.0148","DOIUrl":null,"url":null,"abstract":"<div><p>Magnetization exchange between the solid-wood component and water was studied in hydrated aspen wood by 2D NMR time-domain spectroscopy. Analysis of the relaxation results for exchange shows that a three-site system (water and two wood components) is involved and that the water protons are strongly coupled (a wood-to-water exchange rate of 640 s<sup>−1</sup>) to the water-accessible wood protons, which in turn are less strongly coupled (a wood-to-wood exchange rate of 64 s<sup>−1</sup>) to the water-inaccessible wood protons.</p></div>","PeriodicalId":16130,"journal":{"name":"Journal of Magnetic Resonance, Series B","volume":"113 1","pages":"Pages 1-8"},"PeriodicalIF":0.0000,"publicationDate":"1996-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1006/jmrb.1996.0148","citationCount":"16","resultStr":"{\"title\":\"Interfacial Spin–Spin Coupling in Wood by 2D Time-Domain NMR\",\"authors\":\"D.A. Oleskevich, N. Ghahramany , W.P. Weglarz, H. Peemoeller\",\"doi\":\"10.1006/jmrb.1996.0148\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Magnetization exchange between the solid-wood component and water was studied in hydrated aspen wood by 2D NMR time-domain spectroscopy. Analysis of the relaxation results for exchange shows that a three-site system (water and two wood components) is involved and that the water protons are strongly coupled (a wood-to-water exchange rate of 640 s<sup>−1</sup>) to the water-accessible wood protons, which in turn are less strongly coupled (a wood-to-wood exchange rate of 64 s<sup>−1</sup>) to the water-inaccessible wood protons.</p></div>\",\"PeriodicalId\":16130,\"journal\":{\"name\":\"Journal of Magnetic Resonance, Series B\",\"volume\":\"113 1\",\"pages\":\"Pages 1-8\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1996-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1006/jmrb.1996.0148\",\"citationCount\":\"16\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Magnetic Resonance, Series B\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S106418669690148X\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Magnetic Resonance, Series B","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S106418669690148X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Interfacial Spin–Spin Coupling in Wood by 2D Time-Domain NMR
Magnetization exchange between the solid-wood component and water was studied in hydrated aspen wood by 2D NMR time-domain spectroscopy. Analysis of the relaxation results for exchange shows that a three-site system (water and two wood components) is involved and that the water protons are strongly coupled (a wood-to-water exchange rate of 640 s−1) to the water-accessible wood protons, which in turn are less strongly coupled (a wood-to-wood exchange rate of 64 s−1) to the water-inaccessible wood protons.