二维时域核磁共振研究木材界面自旋-自旋耦合

D.A. Oleskevich, N. Ghahramany , W.P. Weglarz, H. Peemoeller
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引用次数: 16

摘要

利用二维核磁共振时域谱技术研究了水合杨木中实木组分与水之间的磁化交换。对交换松弛结果的分析表明,这是一个三位点系统(水和两种木材成分),水质子与水可及的木材质子强耦合(木-水交换速率为640 s−1),而水可及的木材质子与水不可及的木材质子的耦合较弱(木-木交换速率为64 s−1)。
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Interfacial Spin–Spin Coupling in Wood by 2D Time-Domain NMR

Magnetization exchange between the solid-wood component and water was studied in hydrated aspen wood by 2D NMR time-domain spectroscopy. Analysis of the relaxation results for exchange shows that a three-site system (water and two wood components) is involved and that the water protons are strongly coupled (a wood-to-water exchange rate of 640 s−1) to the water-accessible wood protons, which in turn are less strongly coupled (a wood-to-wood exchange rate of 64 s−1) to the water-inaccessible wood protons.

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