AA-7475/ZrO2/聚合物纳米复合材料的表征及超疏水防腐涂层

4区 材料科学 Q2 Materials Science Journal of Nanomaterials Pub Date : 2023-05-10 DOI:10.1155/2023/8936855
Anil Kumar Bodukuri, A. Kolekar, R. Pandey, Koli Gajanan Chandrashekhar, P. Ram Kumar, K. Anandan, C. Devanathan, Shubhajit Halder, Balkeshwar Singh
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引用次数: 0

摘要

AA-7475涂覆了超疏水(SH)聚合物纳米复合材料(pnc),强调了涂层的制造、表征和防腐品质。用聚氯乙烯(PVC)、硬脂酸铜(CS)和氧化锆(ZrO2)纳米颗粒涂覆AA-7475合金,可产生所需的超疏水性。利用x射线衍射仪、场发射扫描电镜、傅里叶变换红外光谱仪对ZrO2纳米粒子、CS和PVC pnc进行了结构和分子分析。通过分析原子力显微镜图像,确定将ZrO2纳米颗粒的重量百分比从0.6 wt%改变为3.0 wt%时,表面粗糙度对SH行为的影响。含有3.0 wt% ZrO2纳米粒子的PNC-5由于其水接触角为154°,被用作AA-7475的耐腐蚀涂层。在3.5% NaCl溶液中,利用动电位极化和电化学光谱对未包覆和pnc -5包覆的AA-7475进行了研究。PNC-5涂层将AA-7475腐蚀速率从23.75降低到0.2253英里/小时。在本研究中,我们使用极化电阻、耐腐蚀效率、双层电容、腐蚀电流密度和电荷转移电阻来证明SH表面空气捕获现象是有效耐腐蚀的原因。
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Characterization and Superhydrophobic Anticorrosive Coating of AA-7475/ZrO2/Polymer Nanocomposites
An AA-7475 is coated with superhydrophobic (SH) polymer nanocomposites (PNCs), emphasizing the coating’s manufacturing, characterization, and anticorrosive qualities. Coating AA-7475 alloy with polyvinyl chloride (PVC), copper stearate (CS), and zirconium oxide (ZrO2) nanoparticles produces the desired superhydrophobic. Using an X-ray diffractometer, field-emission scanning electron microscopy, Fourier-transform infrared spectrometer, ZrO2 nanoparticles, CS, and PVC PNCs are analyzed structurally and molecularly. The atomic force microscope picture was analyzed to determine how the surface roughness affected the SH behavior reached by changing the weight percentage of ZrO2 nanoparticles from 0.6 to 3.0 wt%. PNC-5 with 3.0 wt% ZrO2 nanoparticles is used as resistance to corrosion coating for AA-7475 due to its water contact angle of 154°. In a 3.5% NaCl solution, uncoated and PNC-5-coated AA-7475 are examined using potentiodynamic polarization and electrochemical spectroscopy. PNC-5 coating reduces AA-7475 corrosion rate from 23.75 to 0.2253 mpy. In this study, we use polarization resistance, corrosion resistance efficiency, double layer capacitance, corrosion current density, and charge transfer resistance to demonstrate that the SH surface air trapping phenomena are responsible for effective corrosion resistance.
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来源期刊
Journal of Nanomaterials
Journal of Nanomaterials 工程技术-材料科学:综合
CiteScore
6.10
自引率
0.00%
发文量
577
审稿时长
2.3 months
期刊介绍: The overall aim of the Journal of Nanomaterials is to bring science and applications together on nanoscale and nanostructured materials with emphasis on synthesis, processing, characterization, and applications of materials containing true nanosize dimensions or nanostructures that enable novel/enhanced properties or functions. It is directed at both academic researchers and practicing engineers. Journal of Nanomaterials will highlight the continued growth and new challenges in nanomaterials science, engineering, and nanotechnology, both for application development and for basic research.
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