{"title":"脂肪酶催化4-羟基-5-十二烷基腈的动力学分解及其在铜金龟子性信息素合成中的应用","authors":"Ei-Ichiro Fukusaki , Shiro Satoda , Shuji Senda , Tetsuo Omata","doi":"10.1016/S0922-338X(98)80161-X","DOIUrl":null,"url":null,"abstract":"<div><p>A facile synthetic method for a cupreous chafer beetle sex pheromone (<em>R,Z</em>)-(−)-5-(1-octenyl)oxacyclopentan-2-one has been developed by employing lipase-catalyzed enantioselective acylation of racemic 4-hydroxy-5-dodecynonitrile in an organic solvent.</p></div>","PeriodicalId":15696,"journal":{"name":"Journal of Fermentation and Bioengineering","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1998-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S0922-338X(98)80161-X","citationCount":"3","resultStr":"{\"title\":\"Lipase-catalyzed kinetic resolution of 4-hydroxy-5-dodecynonitrile and its application to facile synthesis of a cupreous chafer beetle sex pheromone\",\"authors\":\"Ei-Ichiro Fukusaki , Shiro Satoda , Shuji Senda , Tetsuo Omata\",\"doi\":\"10.1016/S0922-338X(98)80161-X\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>A facile synthetic method for a cupreous chafer beetle sex pheromone (<em>R,Z</em>)-(−)-5-(1-octenyl)oxacyclopentan-2-one has been developed by employing lipase-catalyzed enantioselective acylation of racemic 4-hydroxy-5-dodecynonitrile in an organic solvent.</p></div>\",\"PeriodicalId\":15696,\"journal\":{\"name\":\"Journal of Fermentation and Bioengineering\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1998-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S0922-338X(98)80161-X\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Fermentation and Bioengineering\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0922338X9880161X\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Fermentation and Bioengineering","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0922338X9880161X","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Lipase-catalyzed kinetic resolution of 4-hydroxy-5-dodecynonitrile and its application to facile synthesis of a cupreous chafer beetle sex pheromone
A facile synthetic method for a cupreous chafer beetle sex pheromone (R,Z)-(−)-5-(1-octenyl)oxacyclopentan-2-one has been developed by employing lipase-catalyzed enantioselective acylation of racemic 4-hydroxy-5-dodecynonitrile in an organic solvent.
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