聚合物凝胶对137cs和85sr表面去污的研究

P. Luong, N. Chính, N. D. Lam
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引用次数: 6

摘要

该聚合物凝胶溶液由水溶性聚合物优选聚乙烯醇(PVA)、增塑剂(甘油)和螯合剂(柠檬酸)组成,对污染表面的去污效率为137cs和84sr。玻璃和不锈钢、陶瓷和PVC塑料表面的去污效率为95- 99%,也与放射性和涂层厚度有关。最优的膜厚在200微米左右。比较了聚合物凝胶与美国产品decengel 1101在表面上的去污效果。红外光谱研究表明,Cs +和Sr 2+离子通过C=O基团与聚合物凝胶中的PVA和柠檬酸相互作用。这种去污过程的机制已经揭示。
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Surface Decontamination Studies of 137 Cs and 85 Sr Using Polymer Gel
The polymer gel solution consist of water soluble polymer preferably polyvinyl alcohol (PVA), plasticizing agent (glycerine) and chelating agents (citric acid) can decontaminate efficiency of 137 Cs and 84 Sr on the contaminated surfaces. Decontamination efficiency obtained from 95- 99% on glass and stainless steel, ceramic and PVC plastic surfaces, which also depended on radioactivity and coating thickness. Optimization of film thickness is around 200 microns. Decontamination efficiency of Polymer gel were compared with DeconGel 1101 (product from USA) on surfaces. IR spectra studies indicated that Cs + and Sr 2+ ions interacted with PVA and citric acid in Polymer gel through C=O group. Mechanisms of this decontamination process have revealed.
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