HCs5P2W18O62.16H2O吸附有机物亚甲基蓝的合成及应用研究

Salim Koraichi, R. Belghiche, M. Abbessi
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引用次数: 0

摘要

研究了铯道森杂多阴离子HCs5P2W18O62.16H2O对染料亚甲基蓝的吸附。在多相催化中,吸附是一个关键步骤。吸附也可以作为一种分离过程来去除工业废物中可能存在的颜色。第一部分介绍了吸附剂的合成及表征。并对影响吸附的实验参数进行了优化。最后对吸附剂的再生进行了研究。当MB浓度为25 mg/L,吸附剂质量为0.25 g时,收率为88%。在80℃条件下,再生收率为98%。吸附等温线线性化表明,Langmuir模型最适合描述所考虑的现象,因此,反映了整个吸附剂表面活性位点的良好分布。
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Study on Synthesis and Application of HCs5P2W18O62.16H2O to Adsorption of Organic Matter: Methylene Blue
The adsorption of a dye, methylene blue, by a cesium Dawson heteropolyanion HCs5P2W18O62.16H2O, was investigated. In heterogeneous catalysis, adsorption is a crucial step. Adsorption can also be used as a separation process to remove colours that may be present in industrial waste. The first part deals with the synthesis and the characterization of adsorbent. The experimental parameters affecting the adsorption were then optimized. The regeneration of the adsorbent was finally studied. The optimal yield found was 88% for a MB concentration of 25 mg/L and an adsorbent mass of 0.25 g. The yield of the regeneration was 98%, at 80°C. Adsorption isotherms linearization has showed that it is the Langmuir model best suited to describe the considered phenomenon, thus, reflecting a good distribution of active sites across the adsorbent surface.
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