R. Karima, N. Nurmilatina
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引用次数: 0

摘要

通常用作能源的竹炭可以通过添加活化剂和金属掺杂来增加附加值。本研究的目的是分析活化剂的添加和掺杂对生物电池原料电导率和碳特性的影响。实验中使用的竹子有青竹、竹、竹三种。竹材在500 ~ 600℃的温度范围内采用热解法进行炭化。得到的木炭分别用KOH和HNO3两种化学物质活化,然后分别掺杂Zn和Ni。然后,利用高能铣削将得到的碳制成纳米颗粒。采用PSA、SEM、XRD等方法对碳的结构和性能进行了测试;并对其电导率进行了测试。在1030 nm处,经HNO3活化且未掺杂的“buluh”竹炭的粒径最小。竹炭的衍射图和形貌随金属掺杂量的不同而变化。以KOH为活化剂,掺杂Zn的炭的电导率(DHL)最高,为7.02 mS/cm。
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Pengaruh Variasi Aktivator dan Doping terhadap Nilai Daya Hantar Listrik dan Karakterisasi Karbon dari Bambu (Effect of Activator and Doping Variation on The Electrical Conductivity and Carbon Characteristics of Bamboo)
An added value of bamboo charcoal that is commonly used as an energy source could be increased by the addition of activator and metal doping. The objective of this research was to analyze the effect of the addition of activator and doping to the electrical conductivity and carbon characteristics for a raw material of bio-battery. Bamboo plantsused in this experiment were buluh, haur, and betung. Bamboo was carbonized inthe temperature range between 500oC and 600oC by pyrolysis method. Obtained charcoal was activated using two types of chemicals, KOH and HNO3, and then was doped with Zn and Ni. Furthermore, obtained carbon was made into nanoparticles using High Energy Milling. The structure and properties of the carbon were tested using PSA, SEM, and XRD; and the conductivity was also tested. The smallest particle size was obtained from ‘buluh’ bamboo charcoal with HNO3 activation and without a doping at 1030 nm. The diffractogram and topography of the bamboo charcoal varied depending on the metal doping added. The highest electrical conductivity (DHL) was obtained from betung charcoal with an activator of KOH and a doping of Zn at 7.02 mS/cm.
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审稿时长
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