钢筋碱活化混凝土结构腐蚀机理研究进展

Feng Zhang, Xun Xi, Shangtong Yang
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引用次数: 3

摘要

本文综述了近年来碱活化增强材料混凝土结构腐蚀的研究进展。从组成、微观结构和孔隙溶液化学的角度,对比普通硅酸盐水泥(OPC)混凝土,探讨了碳化和氯化物侵入AAMs混凝土的腐蚀机理。钢-碱活化混凝土界面具有不同于OPC混凝土的物理化学特性,是研究钢-碱活化混凝土界面腐蚀起蚀和扩展的关键。此外,还对电化学过程测试方法(包括半电池电位和线性极化电阻)进行了批判性讨论,重点讨论了OPC混凝土可以继承的内容以及由于大多数情况下低估而不再适用于AAMs混凝土的标准。在混凝土结构中应用AAMs替代OPC,迫切需要新的数据和理论。在本文的最后,总结了研究的空白和未来的研究需求,以期AAMs在混凝土结构中的广泛应用,实现可持续低碳建筑。
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Research Progress in Corrosion Mechanism of Reinforced Alkali-Activated Concrete Structures
In this paper, the recent research progress on the corrosion of reinforced alkali-activated materials (AAMs) concrete structures is reviewed. The corrosion mechanisms induced by carbonation and chloride ingress in AAMs concrete are discussed, from the perspectives of composition, microstructure and pore solution chemistry, in comparison to ordinary Portland cement (OPC) concrete. The steel–alkali-activated concrete interface is a key to investigating corrosion initiation and propagation, which has different physical and chemical characteristics of the steel–concrete interface in OPC concrete. Moreover, the electrochemical process testing methods including half-cell potential and linear polarization resistance are critically discussed with a focus on what could be inherited from the OPC concrete and what criteria are no longer suitable for AAMs concrete due to underestimation in most cases. New data and theories are urgently needed for using AAMs in concrete structures to replace OPC. At the end of this paper, the research gaps and future research needs are summarised for the sake of widespread application of AAMs in concrete structures for sustainable and low-carbon construction.
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