{"title":"从 7-oxo-7-deacetoxykhivorin 部分合成 mexicanolide","authors":"J. D. Connolly, Ian M. S. Thornton, D. Taylor","doi":"10.1039/C29710000017","DOIUrl":null,"url":null,"abstract":"7-Oxo-7-deacetoxykhivorin has been transformed into the diene-lactone (XI), a postulated biogenetic precursor of the bicyclonanolide group of tetranortriterpenoids, which when treated with very mild base readily undergoes intramolecular Michael addition to give mexicanolide (XII).","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"23 1","pages":"17-18"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"6","resultStr":"{\"title\":\"Partial synthesis of mexicanolide from 7-oxo-7-deacetoxykhivorin\",\"authors\":\"J. D. Connolly, Ian M. S. Thornton, D. Taylor\",\"doi\":\"10.1039/C29710000017\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"7-Oxo-7-deacetoxykhivorin has been transformed into the diene-lactone (XI), a postulated biogenetic precursor of the bicyclonanolide group of tetranortriterpenoids, which when treated with very mild base readily undergoes intramolecular Michael addition to give mexicanolide (XII).\",\"PeriodicalId\":17278,\"journal\":{\"name\":\"Journal of The Chemical Society D: Chemical Communications\",\"volume\":\"23 1\",\"pages\":\"17-18\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"6\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of The Chemical Society D: Chemical Communications\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/C29710000017\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society D: Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C29710000017","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Partial synthesis of mexicanolide from 7-oxo-7-deacetoxykhivorin
7-Oxo-7-deacetoxykhivorin has been transformed into the diene-lactone (XI), a postulated biogenetic precursor of the bicyclonanolide group of tetranortriterpenoids, which when treated with very mild base readily undergoes intramolecular Michael addition to give mexicanolide (XII).
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