煅烧扇贝壳在水溶液中吸附磷酸盐的研究

Aqidatul Izza, T. Kojima, Y. Amano, M. Machida
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摘要

(CSS),并对其XRD谱、TG / DTA信号和孔隙性质(BET)进行表征。通过间歇式吸附实验,研究了扇贝壳的煅烧温度、pH、吸附时间和浓度对CSS吸附磷酸盐的影响。XRD谱图表明,CaO在800℃煅烧后出现,TG / DTA结果在600 ~ 800℃期间重量下降约38%,BET表面积在800℃煅烧后呈现增大的趋势。在800℃(CSS- 800)煅烧条件下,溶液pH对磷酸盐吸附无显著影响。采用拟一阶和拟二阶模型对CSS- 800吸附数据的动力学模型进行了比较,实验数据与拟二阶动力学模型拟合较好,等温线研究结果接近Langmuir方法,线性回归为0。998年。CSS- 800的吸附量比未煅烧的扇贝壳高30倍。
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Calcined Scallop Shells for Phosphate Adsorption in Aqueous Solution
(CSS), and XRD spectra, TG / DTA signals and pore properties (BET) of CSS were characterized. The influences of calcination temperature of scallop shells, pH, adsorption time and concentration on the phosphate adsorption using CSS were studied in batch adsorption experiment. The XRD spectra showed that CaO appeared after calcination at 800℃ , the TG / DTA result exhibited decreasing weight around 38 % from 600 to 800℃ and BET surface area portrayed increasing value after calcination process at 800℃ . The solution pH on the phosphate adsorption had no significant effect by calcination at 800℃ (CSS- 800 ). A comparison of kinetic models applied to the adsorption data by CSS- 800 was evaluated with pseudo-first order and pseudo-second order model, and the experimental data were fitted well to pseudo-second order kinetic model, while the result of isotherm studies had an approach to Langmuir method with linear regression of 0 . 998 . The adsorption amount of CSS- 800 was 30 times higher than scallop shell without calcination.
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